showing 4 related works from this author
Gold(I)-catalysed cascade reactions in the synthesis of 2,3-fused indole derivatives.
2015
A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.
FeCl3·6H2O-catalyzed Mukaiyama-aldol type reactions of enolizable aldehydes and acetals.
2014
Mukaiyama-aldol type reactions of acetals derived from enolizable aldehydes with FeCl3·6H2O, an eco-friendly, low-cost, and stable catalyst, lead to β-methoxycarbonyl compounds with nearly quantitative yields. The methodology is extended to the parent aldehydes as starting materials, leading to the corresponding aldols with lower yields, but efficiently. Different alkyl and aryl substituted acetals and aldehydes have been tested in the reaction with linear and cyclic silyl enol ethers. Reactions are carried out in an open air atmosphere, and additives are not required. Acetals can be considered activating groups of the carbonyl moiety rather than a protecting group in this type of FeCl3·6H2…
A new family of "clicked" estradiol-based low-molecular-weight gelators having highly symmetry-dependent gelation ability.
2011
Reported herein is the discovery of a novel family of "clicked" estradiol-based LMWGs whose gelation ability highly depends on the gelator symmetry. These LMWGs that gel different organic solvents in the presence of H(2)O even at concentrations as low as 0.04 wt% are readily accessible using "click" chemistry.
CCDC 1061399: Experimental Crystal Structure Determination
2015
Related Article: Ana Gimeno, Alejandra Rodríguez-Gimeno, Ana B. Cuenca, Carmen Ramírez de Arellano, Mercedes Medio-Simón, Gregorio Asensio|2015|Chem.Commun.|51|12384|doi:10.1039/C5CC04606H