0000000000414767

AUTHOR

Maria Rita Caruso

0000-0003-0821-5703

showing 3 related works from this author

Thermal and Mechanical Characterization of Yarn Samples from Flemish Tapestry of the Sixteenth Century

2022

We propose a physico-chemical approach for theharacterization of the conservation condition of yarns from a Flemish tapestry of the sixteenth century. The aging effect on the yarns’ performance was evaluated by comparison with commercial materials. Water uptake experiments highlighted the aptitude of yarns toward water sorption and their increased hydrophilicity upon aging. Thermogravimetric analysis can be considered a fast approach for the fiber identification and assessment on the material life-time. The dynamic mechanical analysis provided direct evidence on the yarns, conservation state and their performance under different mechanical stresses. The proposed characterization path can be…

dynamic mechanical analysisOrganic ChemistryPharmaceutical ScienceWaterthermogravimetryyarn samplesAnalytical ChemistryChemistry (miscellaneous)Settore CHIM/03 - Chimica Generale E InorganicaDrug Discoveryyarn samples; thermogravimetry; dynamic mechanical analysis; water uptakeMolecular MedicineStress MechanicalPhysical and Theoretical Chemistrywater uptakeMolecules; Volume 27; Issue 23; Pages: 8450
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Hydroxypropyl Cellulose Films Filled with Halloysite Nanotubes/Wax Hybrid Microspheres

2021

The design of novel nanocomposite films based on hydroxypropyl cellulose (HPC) and wax/halloysite hybrid microspheres has been reported. In particular, we first prepared wax/clay Pickering emulsions which were characterized by thermogravimetric analysis and microscopy. SEM images allowed more detailed insights on the nanotubes disposition at the wax/water interface, acting as an outer stabilizing shell. Therefore, the cellulosic biopolymer was added, and it was found that HPC enhances the colloidal stability of the particles, preventing their coalescence and sedimentation. The preparation of the composite films was carried out by the solvent casting method, which enabled the development of …

WaxMaterials scienceNanocompositeHydroxypropyl celluloseGeneral Chemical EngineeringHalloysite02 engineering and technologyGeneral Chemistryengineering.material021001 nanoscience & nanotechnologyHalloysiteIndustrial and Manufacturing EngineeringPickering emulsionSettore CHIM/12 - Chimica Dell'Ambiente E Dei Beni CulturaliMicrospherechemistry.chemical_compound020401 chemical engineeringChemical engineeringchemistryvisual_artvisual_art.visual_art_mediumengineering0204 chemical engineering0210 nano-technology
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Halloysite nanotubes-based nanocomposites for the hydrophobization of hydraulic mortar

2021

Abstract The treatment of stone surfaces for their protection from ageing caused by natural and anthropogenic effects is an open issue in materials development for Cultural Heritage. We thought interesting to verify the suitability of a modified cellulose biofilm filled with halloysite nanotubes as wax compatibilizers to design a protecting layer. A hydraulic mortar was selected as a stone prototype. To improve the physico-chemical properties of the covering layer, wax microparticles have been incorporated to control transport, consolidation and wettability features. In particular, different application protocols have been studied, namely brushing and spraying, to assess whether the propos…

WaxMaterials scienceNanocompositeSurfaces and InterfacesGeneral Chemistryengineering.materialMicrostructureHalloysiteSurfaces Coatings and FilmsContact angleColloid and Surface ChemistryAdsorptionvisual_artStone Biopolymer Cultural heritage Halloysite nanotubes Nanocompositesengineeringvisual_art.visual_art_mediumWettingComposite materialMortarSettore CHIM/02 - Chimica FisicaJournal of Coatings Technology and Research
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