Two-dimensional magnetic behaviour in hybrid NiFe-layered double hydroxides by molecular engineering

Layered double hydroxides (LDHs) are a class of two-dimensional (2D) anionic materials that exhibit remarkable chemical versatility, making them ideal building blocks in the design of complex multifunctional materials. In this line, a NiFe-LDH is probably one of the most important LDHs due to its interesting electrochemical and magnetic properties. However, no direct magnetic measurements of exfoliated NiFe-LDH nanosheets have been reported so far. Herein, we synthesize a hybrid NiFe-LDH family through anion exchange reactions using surfactant molecules in order to increase the interlayer space (ranging from 8 to 31.6 Å), minimizing the interlayer dipolar interactions. By intercalation with…