0000000000424405

AUTHOR

M. Brehmer

showing 3 related works from this author

Electroactive Liquid Crystalline Polymers ☆

2017

As with low molecular mass liquid crystals, the polymeric liquid crystalline compounds show many possibilities for interaction with electrical fields. Charge transport via the aromatic cores allows the construction of light emitting devices, field effect transistors and photovoltaic cells. The order of the liquid crystalline phases helps to improve intramolecular charge transfer and the mobility allows easy alignment. Liquid crystalline polymers with ferroelectric phases can be used in fast switching optical devices. Their unique switching mechanism proceeds under reduced interaction with the polymer chains. The combination of liquid crystallinity with elastomer networks leads to electromec…

chemistry.chemical_classificationConductive polymerFerroelectric polymersMaterials sciencebusiness.industryPolymerElastomerFerroelectricityCondensed Matter::Soft Condensed MatterCondensed Matter::Materials ScienceCrystallinitychemistryLiquid crystalElectric fieldOptoelectronicsField-effect transistorbusiness
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Liquid crystalline phases from polymer functionalized ferri-magnetic Fe3O4nanorods

2017

Here, we present the surface functionalization of anisotropic in form ferri-magnetic Fe3O4-nanorods (NRs) with a diblock copolymer, having a PMMA- or PDEGMEMA-block, for solubilization, and a dopamine anchor block. These polymers were synthesized through RAFT polymerization via a macro-initiator approach. The successful surface functionalization, performed via a grafting-to method, was monitored using TGA, IR and TEM measurements. The NRs were very soluble in organic solvents after functionalization. Afterwards, the liquid crystalline (LC) behavior was investigated. During solvent evaporation, birefringent domains were formed. The self-assembly into lyotropic LC structures could be observed…

chemistry.chemical_classificationMaterials scienceNanoparticle02 engineering and technologyGeneral ChemistryPolymer010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceschemistryChemical engineeringPhase (matter)LyotropicMaterials ChemistryCopolymerSurface modificationOrganic chemistryReversible addition−fragmentation chain-transfer polymerizationNanorod0210 nano-technologyJournal of Materials Chemistry C
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CCDC 781606: Experimental Crystal Structure Determination

2016

Related Article: J.-U.Kim, D.Schollmeyer, M.Brehmer, R.Zentel|2011|J.Colloid Interface Sci.|357|428|doi:10.1016/j.jcis.2011.02.006

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(rac)-1-heptan-2-ylureaExperimental 3D Coordinates
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