0000000000429092

AUTHOR

Damiano Sferlazzo

On the radiative impact of aerosols on photolysis rates: comparison of simulations and observations in the Lampedusa island during the ChArMEx/ADRIMED campaign

The Mediterranean basin is characterized by large concentrations of aerosols from both natural and anthropogenic sources. These aerosols affect tropospheric photochemistry by modulating the photolytic rates. Three simulations of the atmospheric composition at basin scale have been performed with the CHIMERE chemistry-transport model for the period from 6 June to 15 July 2013 covered by the ADRIMED campaign, a campaign of intense measurements in the western Mediterranean basin. One simulation takes into account the radiative effect of the aerosols on photochemistry, the second one does not, and the third one is designed to quantify the model sensitivity to a bias in the ozone column. These s…

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A comparison of Microtops II and satellite ozone measurements in the period 2001-2011

Daily average total ozone Microtops measurements obtained during several campaigns conducted from 2001 to 2011 at latitudes from 31 to 68N and in different seasons are compared with satellite observations. The Microtops ozone is derived using different wavelength combinations (Channel I, 305.5/312.5. nm; Channel II, 312.5/320. nm; and Channel III, 305.5/312.5/320. nm). Satellite data from TOMS, OMI, GOME, and GOME-2 are used in the comparison. The three Microtops channels show a high correlation with the satellite retrievals. Channel I shows the best results and produces a mean bias deviation (MBD) less than 2.14% with respect to TOMS, OMI and GOME. The MBD increases to 3% in the comparison…

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Altitude-resolved shortwave and longwave radiative effects of desert dust in the Mediterranean during the GAMARF campaign: Indications of a net daily cooling in the dust layer

Desert dust interacts with shortwave (SW) and longwave (LW) radiation, influencing the Earth radiation budget and the atmospheric vertical structure. Uncertainties on the dust role are large in the LW spectral range, where few measurements are available and the dust optical properties are not well constrained. The first airborne measurements of LW irradiance vertical profiles over the Mediterranean were carried out during the Ground-based and Airborne Measurements of Aerosol Radiative Forcing (GAMARF) campaign, which took place in spring 2008 at the island of Lampedusa. The experiment was aimed at estimating the vertical profiles of the SW and LW aerosol direct radiative forcing (ADRF) and …

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Constraining the ship contribution to the aerosol of the central Mediterranean

Particulate matter with aerodynamic diameters lower than 10 µm, (PM10) aerosol samples were collected during summer 2013 within the framework of the Chemistry and Aerosol Mediterranean Experiment (ChArMEx) at two sites located north (Capo Granitola) and south (Lampedusa Island), respectively, of the main Mediterranean shipping route in the Straight of Sicily. The PM10 samples were collected with 12 h time resolutions at both sites. Selected metals, main anions, cations and elemental and organic carbon were determined. The evolution of soluble V and Ni concentrations (typical markers of heavy fuel oil combustion) was related to meteorology and ship traffic intensity in the Straight of Sicily…

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