0000000000429447

AUTHOR

María Amparo Peiró-ronda

showing 3 related works from this author

Dating archeological lead artifacts from measurement of the corrosion content using the voltammetry of microparticles.

2011

A methodology for dating archeological lead artifacts based on the voltammetry of microparticles is described. This methodology is based on the comparison of the height of speci¿c voltammetric features from PbO2 and PbO corrosion products formed under long-term alteration conditions. Calibration of the method was performed with the help of a series of well-documented lead pieces from the funds of di¿erent museums of the Comunitat Valenciana (Spain) covering from the ¿fth century B.C. to present day. The variation of peak currents with the time of corrosion can be¿tted to the same potential rate law as that found by Reich (R = 0.070 ( 0.005), using measurements on the Meissner fraction in th…

ChemistryElectrodeOxideMineralogyPBO2ArchaeologyAnalytical ChemistryCorrosionSulfuric-acid-solutionBatteriesLead (geology)Electrochemical oxidationAge estimationForce microscopyPINTURACalibrationVoltammetryReductionAnalytical chemistry
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‘Dry’ electrochemistry: A non-invasive approach to the characterization of archaeological iron objects

2021

A methodology for monitoring the corrosion state of archaeological iron objects using ‘dry’ open circuit potential (OCP) measurements is described. Application of this technique to a set of objects from La Bastida de les Alcusses archaeological site (Moixent, València, Spain), dating back to the 4th century BCE, reveals significant differences depending on the conservation state. The transient OCP responses (which last between a few seconds and 10–15 min) were superimposed with much shorter (less than one second) intense features. Fil: Doménech Carbó, Antonio. Universidad de Valencia; España Fil: Peiró Ronda, María Amparo. Museu de Prehistòria de València; España Fil: Vives Ferrándiz, Jaime…

Iron02 engineering and technology010402 general chemistry01 natural sciencesELECTROCHEMISTRYOPEN CIRCUIT POTENTIALElectrochemistryOpen circuit potentialARCHAEOLOGYQD1-999ValenciabiologyIRONNon invasive021001 nanoscience & nanotechnologybiology.organism_classificationArchaeologyTP250-2610104 chemical sciencesCharacterization (materials science)Chemistry//purl.org/becyt/ford/2 [https]ArchaeologyIndustrial electrochemistryTransient (oscillation)//purl.org/becyt/ford/2.5 [https]0210 nano-technologyGeologyElectrochemistry Communications
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Identification of vegetal species in wooden objects using in situ microextraction-assisted voltammetry of microparticles

2017

[EN] A method for identifying vegetal species in wooden objects using microextraction-assisted voltammetry of microparticles is described. The proposed methodology, aimed at facilitating tasks of patrimony conservation, is based on the recording of the voltammetric response of microparticulate films of compounds resulting from microextraction with organic solvents (ethanol, acetone, and chloroform) of micro- or sub-microsamples of wood in contact with aqueous buffers. Upon application of bivariate and multivariate chemometric techniques, the obtained voltammetric responses led us to identify different taxonomic groups from the characteristic voltammetric profiles. Application to a series of…

In situChromatographyChemistryGeneral Chemical Engineering010401 analytical chemistryGeneral EngineeringAnalytical chemistry02 engineering and technology021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesAnalytical ChemistryPINTURA0210 nano-technologyVoltammetry
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