0000000000429613

AUTHOR

James F. Rohan

0000-0003-0415-1140

showing 2 related works from this author

A simulation and experimental study of electrochemical pH control at gold interdigitated electrode arrays

2021

Abstract In electroanalysis, solution pH is a critical parameter that often needs to be tailored and controlled for the detection of particular analytes. This is most commonly performed by the addition of chemicals, such as strong acids or bases. Electrochemical in-situ pH control offers the possibility for the local adjustment of pH at the point of detection, without the need for additional reagents. Finite element analysis (FEA) simulations have been performed on interdigitated electrodes, to guide experimental design in relation to both electroanalysis and in-situ control of solution pH. No previous model exists that describes the generation of protons at an interdigitated electrode arra…

Materials scienceStripping (chemistry)Tailored in-situ pH controlElectroanalysisGeneral Chemical EngineeringAnalytical chemistrySolid state sensorsSquare waveElectrochemistrychemistry.chemical_compoundSettore ING-IND/23 - Chimica Fisica ApplicatachemistryFinite element analysis simulationpH indicatorMethyl redElectrodeElectrochemistryCyclic voltammetryVoltammetryMicroband interdigitated electrode array
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A Theoretical and Experimental Study of Electrochemical pH Control at Gold Interdigitated Microband Arrays

2021

In electroanalysis, solution pH is a critical parameter that often needs to be adjusted and controlled for the detection of particular analytes. This is most commonly performed by the addition of chemicals, such as strong acids or bases. Electrochemical in-situ pH control offers the possibility for the local adjustment of pH at the point of detection, without additional reagents. FEA simulations have been performed to guide experimental design for both electroanalysis and in-situ control of solution pH. No previous model exists that describes the generation of protons at an interdigitated electrode array in buffered solution with one comb acting as a protonator, and the other as the sensor.…

chemistry.chemical_compoundWork (thermodynamics)Materials sciencechemistrypH indicatorReagentMethyl redElectrodeOxideAnalytical chemistryCyclic voltammetryElectrochemistry
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