0000000000429678
AUTHOR
Mohamed-ali Saada
Improved hydrophobicity of inorganic–organic hybrid mesoporous silica with cage-like pores
International audience; Hydrophobic ordered mesoporous silica particles with cage-like pores (SBA-1 type) were prepared through co-condensation of phenyltriethoxysilane (PhTES) and tetraethylorthosilicate (TEOS) at different TEOS/PhTES molar ratios. It is shown that the hydrophobic character of the particles is enhanced by increasing the phenyl loading (decreasing the TEOS/PhTES molar ratio) and that it could be further enhanced by subsequent trimethylsilyl (TMS) grafting on remaining silanol groups (TMS-PhSBA-1 sample). This increase of hydrophobicity has been evidenced on the internal surface (mesoporosity) of the particles using water adsorption and, on the external surface of the partic…
New insights in the formation of silanol defects in silicalite-1 by water intrusion under high pressure.
International audience; The "water-silicalite-1" system is known to act as a molecular spring. The successive intrusion-extrusion cycles of liquid water in small crystallites (6 × 3 × 0.5 μm(3)) of hydrophobic silicalite-1 were studied by volumetric and calorimetric techniques. The experiments displayed a decrease of the intrusion pressure between the first intrusion-extrusion cycle and the consecutive ones, whereas the extrusion pressures remained unchanged. However, neither XRD studies nor SEM observations revealed any structural and morphological modifications of silicalite-1 at the long-range order. Such a shift in the value of the intrusion pressure after the first water intrusion-extr…