Author: Marco Tingoli

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AUTHOR

Marco Tingoli

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Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride

2006

It was found that a mixt. of mol. iodine and 4-iodotoluene difluoride are useful to generate in situ the electrophilic iodine/nucleophilic fluorine (IF) couple that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes.

Settore AGR/13 - Chimica AgrariaOrganic ChemistryDifluorideMarkovnikov's ruleHalogenationchemistry.chemical_elementGeneral MedicineIodineBiochemistrychemistryDrug DiscoveryPolymer chemistryOrganic chemistryHypervalent iodineElectrophilic iodinationFluoroiodoalkanesFluoroiodoalkenesTetrahedron Letters

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