0000000000452234

AUTHOR

Jiri Kucerik

0000-0001-9083-4866

showing 2 related works from this author

Water dynamics and its role in structural hysteresis of dissolved organic matter

2016

Knowledge of structural dynamics of dissolved organic matter (DOM) is of paramount importance for understanding DOM stability and role in the fate of solubilized organic and inorganic compounds (e.g., nutrients and pollutants), either in soils or aquatic systems. In this study, fast field cycling (FFC) (1)H NMR relaxometry was applied to elucidate structural dynamics of terrestrial DOM, represented by two structurally contrasting DOM models such as Suwanee River (SRFA) and Pahokee peat (PPFA) fulvic acids purchased by the International Humic Substance Society. Measurement of NMR relaxation rate of water protons in heating-cooling cycles revealed structural hysteresis in both fulvic acids. I…

Magnetic Resonance SpectroscopyrelaxometrySettore AGR/13 - Chimica Agraria010501 environmental sciences01 natural scienceshumic substanceSoilRiversDissolved organic carbonEnvironmental ChemistryReactivity (chemistry)Benzopyrans0105 earth and related environmental sciencesChemistryHydrogen bondwater histeresiChemical polarityTemperatureSoil chemistryWaterHydrogen Bonding04 agricultural and veterinary sciencesGeneral ChemistryNuclear magnetic resonance spectroscopyEnvironmental chemistrySoil water040103 agronomy & agricultureProton NMR0401 agriculture forestry and fisheriesHydrophobic and Hydrophilic Interactions
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Effect of Heating Time and Temperature on the Chemical Characteristics of Biochar from Poultry Manure

2014

Poultry manure (PM) chars were obtained at different temperatures and charring times. Chemical-physical characterization of the different PM chars was conducted by cross-polarization magic angle spinning (CPMAS) (13)C NMR spectroscopy and thermal analysis. CPMAS (13)C NMR spectra showed that the chemical composition of PM char is dependent on production temperature rather than on production duration. Aromatic and alkyl domains in the PM chars obtained at the lowest temperatures remained unchanged at all heating times applied for their production. The PM char obtained at the highest temperature consisted only of aromatic structures having chemical nature that also appeared invariant with hea…

chemistry.chemical_classificationHot TemperatureMagnetic Resonance SpectroscopyTime FactorsSettore AGR/13 - Chimica AgrariaAnalytical chemistryGeneral ChemistryPoultryManureThermogravimetrychar poultry manure CPMAS 13C NMR TGA DTG thermal stabilitychemistryCharcoalSpectroscopy Fourier Transform InfraredBiocharMagic angle spinningAnimalsOrganic chemistryCharringCharGeneral Agricultural and Biological SciencesThermal analysisChemical compositionAlkyl
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