0000000000460902

AUTHOR

Alessia Bacchi

0000-0001-5675-9372

showing 11 related works from this author

Coordination Driven Capture of Nicotine Inside a Mesoporous MOF.

2017

Metal organic frameworks (MOFs) are a wide class of crystalline porous polymers studied in many fields, ranging from catalysis to gas storage. In the past few years, MOFs have been studied for the encapsulation of organic or organometallic molecules and for the development of potential drug carriers. Here, we report on the study of two structurally-related mesoporous Cu-MOFs, namely PCN-6 and PCN-6′ (PCN stands for Porous Coordination Network), for nicotine trapping. Nicotine is a well-known alkaloid liquid molecule at room temperature, whose crystalline structure is still unknown. In this work, the loading process was monitored by electron ionization mass spectrometry by using a direct ins…

Thermogravimetric analysiscrystalline sponge02 engineering and technologyCrystal structure010402 general chemistryPhotochemistryMass spectrometrylcsh:Technology01 natural sciencesArticlechemistry.chemical_compoundPyridineMoleculeOrganic chemistryGeneral Materials Sciencelcsh:MicroscopyElectron ionizationlcsh:QC120-168.85MOFhost-guestlcsh:QH201-278.5lcsh:TMOF; nicotine; crystalline sponge; inclusion; host-guest021001 nanoscience & nanotechnology0104 chemical sciencesinclusionchemistrylcsh:TA1-2040lcsh:Descriptive and experimental mechanicsMetal-organic frameworklcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)0210 nano-technologyMesoporous materiallcsh:TK1-9971nicotineMaterials (Basel, Switzerland)
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Synthesis and antimicrobial activity of new 3-(1-R-3(5)-methyl-4-nitroso-1H-5(3)-pyrazolyl)-5-methylisoxazoles.

2000

A number of new 3-(1-R-3(5)-methyl-4-nitroso-1H-5(3)-pyrazolyl)-5-methylisoxazoles 6a-g (7b-f) were synthesized and tested for antibacterial and antifungal activity. Some of these compounds displayed antifungal activity at non-cytotoxic concentrations. Derivative 6c was 9 times more potent in vitro than miconazole and 20 times more selective against C. neoformans. 6c was also 8- and 125-fold more potent than amphotericin B and fluconazole, respectively. None of the compounds was active against bacteria. Preliminary structure-activity relationship (SAR) studies showed that the NO group at position 4 of the pyrazole ring is essential for the activity. Lipophilicity of the pyrazole moiety, N-a…

Antifungal AgentsStereochemistryClinical BiochemistryPharmaceutical ScienceMicrobial Sensitivity TestsPyrazoleGram-Positive BacteriaBiochemistryChemical synthesischemistry.chemical_compoundStructure-Activity RelationshipAnti-Infective AgentsDrug DiscoveryGram-Negative BacteriamedicineMoietyHumansCytotoxicityMolecular BiologyChemistryOrganic ChemistryFungiNitrosoIsoxazolesAntimicrobialAnti-Bacterial AgentsLipophilicityCryptococcus neoformansHIV-1Molecular MedicineMiconazolemedicine.drugBioorganicmedicinal chemistry
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Mononuclear and polynuclear complexes ligated by an iminodiacetic acid derivative: synthesis, structure, solution studies and magnetic properties

2016

Two novel families of coordination polymers, [Ln(bzlida)(Hbzlida)]·H2O (Ln = La, Nd) and [Ln2(bzlida)3]·3H2O (Ln = Nd, Sm, Eu, Gd) were prepared by hydrothermal reaction of Ln2O3 with benzyliminodiacetic acid (H2bzlida). The conditions of synthesis, in particular the pH value, were selected on the basis of previous speciation studies reported in this work. The first type of complex consists of 1D chains built by a fully deprotonated ligand bridging two lanthanide ions and protonated Hbzlida(-) ligands connecting three cations. The second type is formed by [Ln2(bzlida)3] bimetallic units in which the ligand has a tridentate NOO coordination mode. This is expanded to a 2D network through carb…

Lanthanide010405 organic chemistryIminodiacetic acidStereochemistryLigandProtonation010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographyMonomerDeprotonationchemistryCarboxylateBimetallic stripDalton Transactions
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CCDC 1400954: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(tris(mu3-22'-(Benzylimino)diacetato)-triaqua-di-gadolinium)Cell ParametersExperimental 3D Coordinates
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CCDC 1400958: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-22'-(Benzylimino)diacetato)-bis(acetato-OO')-deca-aqua-copper-di-erbium bis(22'-(benzylimino)diacetato)-copper hexahydrateExperimental 3D Coordinates
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CCDC 1400956: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

Space GroupCrystallographycatena-((mu3-22'-(Benzyliminio)diacetato)-(mu2-22'-(benzylimino)diacetato)-aqua-lanthanum)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1400955: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-22'-(benzylimino)diacetato)-triaqua-di-samarium]Experimental 3D Coordinates
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CCDC 1400953: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(tris(mu-22'-(benzylimino)diacetato)-triaqua-di-europium)Cell ParametersExperimental 3D Coordinates
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CCDC 1555580: Experimental Crystal Structure Determination

2018

Related Article: Davide Balestri, Davide Capucci, Nicola Demitri, Alessia Bacchi, Paolo Pelagatti|2017|Materials|10|727|doi:10.3390/ma10070727

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[octakis(mu-44'4''-(135-triazine-246-triyl)tribenzoato)-dodecakis(3-(1-methylpyrrolidin-2-yl)pyridine)-dodeca-copper unknown solvate]
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CCDC 1400957: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

bis(Hydrogen 22'-(benzylimino)diacetato)-copper(ii) unknown solvate tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1400952: Experimental Crystal Structure Determination

2016

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

Space GroupCrystallographycatena-(tris(mu3-22'-(Benzylimino)diacetato)-triaqua-di-neodymium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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