0000000000461729
AUTHOR
Wei Cui
Fluorescent-Cavity Host: An Efficient Probe to Study Supramolecular Recognition Mechanisms
Using fluorometry to study the interactions between guests and host cavities is often challenging, especially for hosts with small cavities because the fluorophore may not be close to the binding site. Therefore, it is critical to overcome this hurdle to broaden the applicability of fluorometry in supramolecular chemistry. Herein, we designed a fluorescent-cavity host (H1) by conjugating the binding site of a pillar[5]arene cavity and studied its host-guest recognition mechanism in the cavity. Distinct fluorescent responses of H1 were observed for cyano homologues: the fluorescence was enhanced for succinonitrile but quenched for malononitrile. Such an unusual phenomenon with such subtle di…
Accretion in strong field gravity with eXTP
In this paper we describe the potential of the enhanced X-ray Timing and Polarimetry (eXTP) mission for studies related to accretion flows in the strong field gravity regime around both stellar-mass and supermassive black-holes. eXTP has the unique capability of using advanced 'spectral-timing-polarimetry' techniques to analyze the rapid variations with three orthogonal diagnostics of the flow and its geometry, yielding unprecedented insight into the inner accreting regions, the effects of strong field gravity on the material within them and the powerful outflows which are driven by the accretion process.
Multiband variability studies and novel broadband SED modeling of Mrk 501 in 2009
Astronomy and astrophysics 603, A31 (2017). doi:10.1051/0004-6361/201629540
Pillar[5]arene-Diketopyrrolopyrrole Fluorescent Copolymer: A Promising Recognition and Adsorption Material for Adiponitrile by Selective Formation of a Conjugated Polypseudorotaxane
Conjugated pillar[5]arene-diketopyrrolopyrrole copolymer (P1) is synthesized by the copolymerization of a difunctionalized pillar[5]arene and a diketopyrrolopyrrole-based monomer, which shows large extinction coefficients (1.1 × 104 m-1 cm-1 ) at 519 nm and strong emission at 587 nm. P1 exhibits very strong host-guest binding affinity towards adiponitrile but low binding affinity towards 1,4-dihalobutane and 1,4-bis(imidazol-1-yl)butane. Such an enhanced selectivity is first found in the polypseudorotaxane between pillararene and neutral guests in organic solution and is successfully used for the recognition and adsorption of adiponitrile by the formation of a P1-adiponitrile polypseudorota…
The large-scale environment from cosmological simulations II: The redshift evolution and distributions of baryons
Following Cui et al. 2018 (hereafter Paper I) on the classification of large-scale environments (LSE) at z = 0, we push our analysis to higher redshifts and study the evolution of LSE and the baryon distributions in them. Our aim is to investigate how baryons affect the LSE as a function of redshift. In agreement with Paper I, the baryon models have negligible effect on the LSE over all investigated redshifts. We further validate the conclusion obtained in Paper I that the gas web is an unbiased tracer of total matter -- even better at high redshifts. By separating the gas mainly by temperature, we find that about 40 per cent of gas is in the so-called warm-hot intergalactic medium (WHIM). …
A conjugated polymer with ethyl 2-(2-(pyridin-2-yl)-1H-benzo[d]imidazol-1-yl) acetate units as a novel fluorescent chemosensor for silver(I) detection
Abstract A novel conjugated polymer ( P1 ) containing fluorene and ethyl 2-(2-(pyridin-2-yl)-1 H -benzo[ d ]imidazol-1-yl)acetate (PBMA) was designed and successfully synthesized through the Sonogashira coupling reaction. P1 shows high sensitivity and selectivity for Ag + detection in comparison to other metal cations. Upon addition of Ag + , the fluorescent emission of the polymer solution in THF was quenched dramatically, accompanying the color changed from blue to green. The detection limit for Ag + was 5 × 10 −8 mol L −1 . However, the similar copolymers P2 and P3 containing 2-(pyridin-2-yl)-1 H -benzo[ d ]imidazole and 2-(thiophen-2-yl)-1 H -benzo[ d ]imidazole, respectively, did not …
The enhanced X-ray Timing and Polarimetry mission—eXTP
In this paper we present the enhanced X-ray Timing and Polarimetry mission - eXTP. eXTP is a space science mission designed to study fundamental physics under extreme conditions of density, gravity and magnetism. The mission aims at determining the equation of state of matter at supra-nuclear density, measuring effects of QED, and understanding the dynamics of matter in strong-field gravity. In addition to investigating fundamental physics, eXTP will be a very powerful observatory for astrophysics that will provide observations of unprecedented quality on a variety of galactic and extragalactic objects. In particular, its wide field monitoring capabilities will be highly instrumental to det…
Stronger host-guest binding does not necessarily give brighter particles: a case study on polymeric AIEE-tunable and size-tunable supraspheres.
Supraspheres were prepared from a pillar[5]arene-based linear polymer (the host) and several multitopic guests. According to host-guest binding studies in nanosystems, the optical and structural properties (fluorescence capability, density, and particle size) of the nanoparticles were correlated not with the host-guest binding affinities, but with the relative fluorescence quantum yield.
OUP accepted manuscript
Following Cui et al. 2018 (hereafter Paper I) on the classification of large-scale environments (LSE) at z = 0, we push our analysis to higher redshifts and study the evolution of LSE and the baryon distributions in them. Our aim is to investigate how baryons affect the LSE as a function of redshift. In agreement with Paper I, the baryon models have negligible effect on the LSE over all investigated redshifts. We further validate the conclusion obtained in Paper I that the gas web is an unbiased tracer of total matter -- even better at high redshifts. By separating the gas mainly by temperature, we find that about 40 per cent of gas is in the so-called warm-hot intergalactic medium (WHIM). …
CCDC 1811268: Experimental Crystal Structure Determination
Related Article: Wei Cui, Lingyun Wang, Linxian Xu, Guozhen Zhang, Herbert Meier, Hao Tang, Derong Cao|2018|J.Phys.Chem.Lett.|9|1047|doi:10.1021/acs.jpclett.8b00037