Integrated modelling of membrane deformation, fluid dynamics and mass transfer in electromembrane processes

In recent years, water and energy supply issues have drawn the attention of the scientific community to electromembrane processes. Electrodialysis (ED) and Reverse Electrodialysis (RED) are two of the most attractive electromembrane technologies for water desalination and electric energy production from salinity gradients, respectively. In order to gain an important place in the industrial market, technological challenges on various aspects are involved in the optimization of these processes. In this context, profiled membranes exhibit interesting performance. However, the mechanical behavior of the membranes and its interaction with fluid dynamics has been poorly investigated so far. In me…

Experimental Analysis via Thermochromic Liquid Crystals of the Temperature Local Distribution in Membrane Distillation Modules

2013

A reliable and optimized design of channels for Membrane Distillation (MD) requires knowledge of local temperature distributions within the module. This information is essential to measure the temperature polarization, choice the module configuration (net spacer features, channel size, etc) providing the best process performance. Notwithstanding such crucial aspects, only few studies have been devoted to the experimental characterization of MD channels and none of them includes data on the local temperature distribution. In the present work, an experimental technique based on the use of Thermochromic Liquid Crystals (TLCs) and digital image processing, previously proposed by the authors (Pi…

Two-dimensional model of cross-flow electrodialysis units for the assessment of membrane deformation effects on the process performance

Volume and number average sizes of Mg(OH)2 particles from concentrated Mg2+ containing solutions

Influence of bundle porosity on shell-side hydrodynamics and mass transfer in regular fiber arrays: A computational study

2023

CFD predictions of the effects of a fiber bundle porosity on shell-side hydrodynamics and mass transfer under conditions of steady laminar flow were obtained. Fluid was assumed to flow around regular hexag-onal or square arrays of cylindrical fibers of different pitch to diameter ratios, yielding bundle porosities ranging from the theoretical minimum up to similar to 1. A large number of axial, transverse and mixed flow combinations were simulated by letting the axial and transverse flow Reynolds numbers and the trans-verse flow attack angle vary. Both fully developed and developing conditions (entrance effects) were con-sidered. The continuity and momentum equations, along with a transport…

A process model of electrodialysis including membrane deformation effects

2020

Electrodialysis (ED) is an electro-driven process that makes use of ion exchange membranes (IEMs) under an applied electric field. The main application of ED is the desalination for drinking water production. A transmembrane pressure (TMP) distribution may arise in ED stacks due to an uneven pressure distribution in the two fluid channels, thus causing membrane/channel deformation and flow redistribution. This can occur in large-scale non-parallel configurations, e.g. crossflow arrangements. Detrimental effects of membrane deformation have widely been studied with reference to several membrane processes. However, this aspect has been neglected in ED applications. In this work, a novel proce…

Mass transfer in channels in the presence of wall transpiration

Mass transfer to or from transpiring walls is studied. Examples from different fields of engineering, notably involving membrane processes, are illustrated, and analogies or differences with respect to heat transfer problems are discussed. With special reference to plane channel flow, suitable dimensionless parameters are introduced, and the dependence of the Sherwood number upon these parameters is computed by a number of approaches of different complexity, from two-dimensional CFD to simple algebraic correlations.

Heat-transfer performance comparison between overlapped and woven spacers for membrane distillation

2016

Sustainable production of fresh water from seawater desalination is a problem of crucial importance nowadays. Recently, some desalination technologies are taking advantage from the coupling with renewable resources. Among emerging technologies, Membrane Distillation (MD) is considered as one of the most promising as it can be easily powered by solar thermal energy or waste-heat. As an emerging technology, efforts are required to optimize MD unit geometry and operating conditions in order to reduce fresh water production specific cost. Temperature polarization phenomenon is a well-known detrimental effect for the MD process. Spacers are traditionally used to enhance mixing and shrink tempera…

Developments in numerical modelling of cardiovascular fluid dynamics

1998

CFD Simulation of Mass Transfer Phenomena in Spacer Filled Channels for Reverse Electrodialysis Applications

2013

Salinity Gradient Power via Reverse Electrodialysis is a topic of primary importance nowadays. It allows getting energy from the “controlled” mixing of solutions at different salt concentration. The performance of this technology depends on many factors such as: components properties (i.e. membranes, spacers, electrodes), stack geometry, operating conditions and feeds features. Concentration polarization phenomena may significantly affect the actual membrane potential, thus reducing the gross power produced. On the other hand, C-polarization phenomena may significantly be reduced by suitably choosing the hydrodynamic regime within the stack. Such a choice may in turn significantly require h…

A multi-physics modelling tool for Reverse Electrodialysis

2015

In this work, a multi-physics modelling approach has been developed for the RED process.

Dense Solid-Liquid Off-Bottom Suspension Dynamics: Simulation and Experiment

2009

Dense solid-liquid off-bottom suspension inside a baffled mechanically agitated stirred tank equipped with a standard Rushton turbine is investigated. Dynamic evolution of the suspension from start up to steady state conditions has been inspected by both visual experiments and computational fluid dynamics. A classical Eulerian-Eulerian Multi Fluid Model along with the “homogeneous” k-epsilon turbulence model is adopted to simulate suspension dynamics. In these systems the drag inter-phase force affects both solids suspension and distribution. Therefore, different computational approaches are tested in order to compute this term. Simulation results are compared with images acquired on the re…

Application of computational fluid dynamics technique in membrane distillation processes

2022

This Chapter illustrates the application of CFD to spacer-filled channels for membrane distillation. The topics discussed cover finite volume grids and grid independence, the unit-cell treatment of spatially periodic net spacers, and the dependence of flow and thermal fields and overall performance parameters (pressure drop and mean heat transfer coefficients) upon geometry and operating conditions (Reynolds number, flow attack angle, pitch-to-height ratio, spacer thermal conductivity, thermal boundary conditions, and one-side vs. two-side heat transfer).

Coupling CFD simulation with a simplified process model for reverse electrodialysis units

2017

Salinity gradient between two solutions is a renewable source of energy. Among the technologies able to exploit the salinity gradient, reverse electrodialysis (RED) is an electrochemical process for electrical power generation through direct conversion. Ion exchange membranes, piled alternately and separated by net spacers or membrane profiles, are the key elements of a RED stack. A multiplex phenomenology occurs in RED units; Ohmic and non-Ohmic (due to concentration changes) voltage losses and pressure drop are the main issues, and the membrane/channel configuration is crucial for the stack performance. In this framework, mathematical modelling can be a powerful tool for predictive purpos…

CFD PREDICTION OF SCALAR TRANPORT IN THIN CHANNELS FOR REVERSE ELECTRODIALYSIS

2014

Reverse ElectroDialysis (RED) is a very promising technology allowing the electrochemical potential difference of a salinity gradient to be directly converted into electric energy. Fluid dynamics optimization of the thin channels to be devoted for the RED process is still an open problem. The present preliminary work focuses on the Computational Fluid Dynamics (CFD) simulation of the flow and concentration fields in these channels. In particular three different configurations were investigated: a channel unprovided with a spacer and two different spacer (made of either overlapped filaments or woven filaments) filled channels. Two passive scalars were transported along with the water in orde…

Application of computational fluid dynamics technique in electrodialysis/reverse electrodialysis processes

2022

This Chapter treats the application of CFD technique in ED/RED processes. CFD simulations are able to predict flow and mass transfer in channels filled with spacers or membrane profiles, by providing dimensionless correlations useful for process models. At a larger scale, manifolds of the stack and inlet/ outlet zones of the channel can be simulated. Numerical models can include the computation of the electrical potential, thus characterizing the process performance. Direct numerical simulations can elucidate the complex phenomenology of overlimiting transport and of chaotic electrokinetic flows.

Computational Study on the Gas-Phase and Aqueous Solution Acidity of Nicotine

2017

Dielectric continuum solvation models (1), recently introduced in the routine of computational chemistry, have allowed organic chemists to afford solvation free energies, thus getting a closer insight on the real thermodynamics of chemical reactions in solution. Hydron transfer reactions are by far the most studied due to their importance both in physico-chemical systems and in synthetic applications. Since, on the other hand, molecules have almost always a notable molecular flexibility, each computational assessment should certainly address an accurate conformational analysis of each species involved in the chemical equilibrium. This rather annoying and troublesome complication has been au…