0000000000470800
AUTHOR
G. Barochi
Development of microwave gas sensors
Abstract This work presents a novel approach in gas detection by an original method of microwave transduction. The design of the sensor includes a coplanar grounded wave guide with a gas sensing material to study its sensitivity to ammonia in argon flux. The sensing material can play the role of the substrate or can be deposited as a thin layer on a microstrip structure used in electronics. Submitted to an electromagnetic excitation in microwave energies, the sensor response in the presence of a gas results in a specific modification of the reflected wave (real and imaginary parts). The goals of this study include an examination of the form of the sensitive material and its influence on the…
The multimodal detection as a tool for molecular material-based gas sensing
Abstract The adsorption of a target gas on a material induces a change in several physical characteristics, such as the dielectric constant, the work function or the conductivity. The use of different transducers sensitive to the variation of these parameters appears to be a relevant methodology worthy of investigation. In the field of sensors, molecular materials present interesting and potentially valuable features as sensing elements for real gas sensor applications. In this article, we review the different types of conductimetric transducers and also show how a molecular material-based microwave transducer can be used for gas sensing. Among conductimetric transducers, resistors have bee…
Microwave-based gas sensor with phthalocyanine film at room temperature
Abstract This work presents the development of a microwave gas sensor at room temperature. The design of the sensor includes a coplanar grounded wave guide where is deposited a molecular gas sensing material. In this study, the sensitive material is a thin layer of cobalt phthalocyanine (CoPc), sensitive to ammonia and toluene. Submitted to an electromagnetic incident wave in the microwave range, the sensor response is a reflected wave. In the presence of pollutant, the reflected wave shape is specific to the species concentrations. The results interpretation is led at each frequency by the evaluation of the reflected coefficient, which traduces the ratio between the reflected wave over the…
Development of gas sensors by microwave transduction with phthalocyanine film
International audience; This work presents a new transduction mode for gas sensing using a passive microwave circuit at room temperature. The design of the sensor includes a microstrip line where is deposited a thin molecular layer of cobalt phthalocyanine (CoPc). The material is sensitive to ammonia and toluene. Submitted to an electromagnetic incident wave in the microwave range, the sensor response is a reflected wave. In the presence of ammonia, the reflected wave is specific to the species concentration. The sensor response is the reflected wave over the incident wave ratio at each frequency traduced by the reflected coefficient. The study deals with the influence of molecular sensitiv…
Differential study of substituted and unsubstituted cobalt phthalocyanines for gas sensor applications
Abstract The conductivity of CoPc (cobalt phthalocyanine) and Co[(SO3Na)2,3Pc] was measured under a flow of two different gases (NH3 and O3), during exposure/recovery cycles. It appears that the relative responses are linearly related to the concentration, in the 20–200 ppb range for O3 and in the 20–200 ppm range for NH3. Observed during time, the sensing parameters allow a qualitative understanding of the kinetics. The comparative study of those products under both different gases gave interesting results for sensor applications. Whereas CoPc is sensitive to both gases, its sulfonated counterpart is only sensitive to NH3.
Enhanced chemosensing of ammonia based on the novel molecular semiconductor-doped insulator (MSDI) heterojunctions
Abstract A series of new molecular semiconductor-doped insulator (MSDI) heterojunctions as conductimetric transducers to NH3 sensing were fabricated based on a novel semiconducting molecular material, an amphiphilic tris(phthalocyaninato) rare earth triple-decker complex, Eu2[Pc(15C5)4]2[Pc(OC10H21)8], quasi-Langmuir–Shafer (QLS) film, as a top-layer, and vacuum-deposited and cast film of CuPc as well as copper tetra-tert-butyl phthalocyanine (CuTTBPc) QLS film as a sub-layer, named as MSDIs 1, 2 and 3, respectively. MSDIs 1–3 and respective sub-layers prepared from three different methods were characterized by X-ray diffraction, electronic absorption spectra and current–voltage (I–V) measu…