0000000000471145

AUTHOR

Vincenzo Vaiano

0000-0002-2205-7871

showing 2 related works from this author

Highly robust and selective system for water pollutants removal: How to transform a traditional photocatalyst into a highly robust and selective syst…

2019

Highly porous monolithic aerogels based on ZnO photocatalyst and syndiotactic polystyrene (s-PS) were obtained by supercritical CO2 treatment of ZnO/s-PS gels. The prepared aerogels were characterized and their photocatalytic activity was evaluated using phenol and toluene as water pollutant models. The s-PS nanoporous crystalline phase, able to absorb pollutant molecules, was proven to be necessary to ensure high photocatalytic efficiency as the aerogel acts not only as a support, but also as pollutant pre-concentrator. The reusability of ZnO/s-PS aerogels is also strong showing no decrease in photocatalytic activity after six consecutive degradation trials. Finally, the aerogel matrix pre…

PollutantNanoporous crystalline phasesMaterials scienceWater pollutants photodegradationNanoporousGeneral Chemical EngineeringAerogelsAerogelArticleSupercritical fluidlcsh:Chemistrychemistry.chemical_compoundlcsh:QD1-999chemistryChemical engineeringPhotocatalyst supportPhotocatalysisZnODegradation (geology)General Materials SciencePolystyreneDissolutionAerogels; Nanoporous crystalline phases; Photocatalyst support; Water pollutants photodegradation; ZnO
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Keggin heteropolyacid supported on TiO2 used in gas-solid (photo)catalytic propene hydration and in liquid-solid photocatalytic glycerol dehydration

2017

Abstract (Photo)catalytic propene hydration to 2-propanol and glycerol dehydration to acrolein were carried out by using Keggin heteropolyacids (HPAs) supported on TiO 2 . Binary materials have been prepared by impregnation of H 3 PW 12 O 40 , H 3 PMo 12 O 40 and H 4 SiW 12 O 40 , on TiO 2 Evonik P25. Moreover, a binary material consisting of H 4 SiW 12 O 40 and TiO 2 was prepared via a hydrothermal treatment and tested for the same reactions. All the materials were characterized by X-ray diffraction (XRD), scanning electron microscopy observations (SEM) coupled with energy dispersive X-ray (EDX) measurements, diffuse reflectance spectroscopy (DRS), Raman spectroscopy and Fourier transform …

GlycerolDiffuse reflectance infrared fourier transformScanning electron microscopeInorganic chemistry02 engineering and technology010402 general chemistry01 natural sciencesPropeneCatalysisCatalysiCatalysisPropenechemistry.chemical_compoundsymbols.namesakePhotocatalysiGlycerol; Heteropolyacid; Photocatalysis; Polyoxometalate; Propene; Catalysis; Chemistry (all)Fourier transform infrared spectroscopyPhotocatalysisPolyoxometalateHeteropolyacid propene glycerolAcroleinChemistry (all)General ChemistryHeteropolyacid021001 nanoscience & nanotechnology0104 chemical scienceschemistrysymbolsPhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyRaman spectroscopy
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