0000000000486179
AUTHOR
S. Di Tommaso
Acridine orange in a pumpkin-shaped macrocycle: Beyond solvent effects in the UV–visible spectra simulation of dyes
Abstract We present simulation of the UV–visible spectra of acridine orange, a widely used photosensitizer for in vivo studies due to its highly environment-dependent spectroscopic properties. This dye has been investigated both in its protonated and neutral forms, either isolated or embedded in a pumpkin-shaped macromolecular cycle (cucurbit-7-uril), using time-dependent density functional theory techniques. To model this macromolecular cycle, two strategies are taken into account, allowing decoupling of the geometric and electrostatic influences of the host on the guest molecules. Experimental data are well-reproduced when using an embedding electrostatic technique, suggesting that such a…
Active power maximizing for Wind Electrical Energy Generating Systems moved by a Modular Multiple Blade Fixed Pitch Wind Turbine
This paper proposes a new solution for wind electrical energy generating system (WEEGS). The system here taken into account is moved by a modular multiple blade fixed pitch wind turbine (MMBFPWT) and foresees a new MPPT algorithm whose main characteristics are low cost, low noise, buildings simplicity and modularity. The mathematical model of the entire WEEGS has been here developed taking into account all the components starting from the wind turbine and ending with the electrical grid. The WEEGS mathematical model has been implemented in Matlab-Simulink in order to carry out the simulations needed to test the effectiveness of the proposed WEEGS. The simulations results show the effectiven…