0000000000524043

AUTHOR

Cédric Balan

showing 58 related works from this author

Titanium imido complexes stabilised by bis(iminophosphoranyl)methanide ligands: the influence of N-substituents on solution dynamics and reactivity

2014

Terminal titanium imido complexes of the general formula [Ti(N(t)Bu)Cl{CH(Ph2PNR)2}] 4 (R = Ph, (i)Pr, (t)Bu) are reported. These compounds were synthesized from the corresponding Li adducts 3 of BIPMH (bis(iminophosphoranyl)methanide) and Mountford's complex [Ti(N(t)Bu)Cl2(Py)3]. The crystal structures of two of the Ti complexes (R = Ph, (t)Bu) and two of the Li compounds (R = (i)Pr, (t)Bu) are reported. Dynamic solution NMR spectroscopy reveals a dynamic isomerisation process in the case of the Ti complex 4c (R = (t)Bu). DFT studies showed that this dynamic process comes from steric repulsion between the imido ligand and the (t)Bu N-substituents on the BIPMH ligand. Complexes 4 were teste…

chemistry.chemical_classificationLigandAlkyneNuclear magnetic resonance spectroscopyCrystal structurePhotochemistryMedicinal chemistryAdductInorganic Chemistrychemistry.chemical_compoundchemistryPhenylacetyleneReactivity (chemistry)Hydroamination[CHIM.OTHE]Chemical Sciences/OtherComputingMilieux_MISCELLANEOUS
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Atom Transfer Radical Addition Catalyzed by Ruthenium–Arene Complexes Bearing a Hybrid Phosphine–Diene Ligand

2018

International audience; The synthesis and characterization of a series of arene ruthenium complexes bearing either (3,5-cycloheptadienyl)diphenylphosphine or (cycloheptyl)-diphenylphosphine are reported. Upon irradiation or heating, all these complexes lose their arene ligand but then exhibit a different behavior depending on the nature of the phosphine ligand. (Cycloheptadienyl)phosphine complexes 1 and 3 give a cationic dinuclear Ru complex 5 for which the two Ru atoms are bridged by three chlorido ligands and flanked by two tridendate (cycloheptadienyl)phosphines. (Cycloheptyl)-diphenylphosphine complexes 2 and 4 undergo arene exchange when toluene is used as solvent or degrade in dithlo…

Dieneeffective core potentialsprecursorchemistry.chemical_element010402 general chemistrychemistry01 natural sciencesMedicinal chemistryAdductInorganic Chemistrychemistry.chemical_compoundMoiety[CHIM.COOR]Chemical Sciences/Coordination chemistryarylationPhysical and Theoretical ChemistryDiphenylphosphine010405 organic chemistryAtom-transfer radical-polymerizationLigand[CHIM.ORGA]Chemical Sciences/Organic chemistryOrganic Chemistry[CHIM.CATA]Chemical Sciences/Catalysismolecular calculations0104 chemical sciencesRutheniumkharasch reactionatrc reactionschemistrypolymerizationpincer complexesmetathesisPhosphine
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Phenoxyamidine Zn and Al Complexes: Synthesis, Characterization, and Use in the Ring-Opening Polymerization of Lactide

2019

International audience; Herein we report the synthesis of new ditopic ligands, which consist of a phenoxy group and N,N,N'trisubstituted amidines linked by a methylene spacer (L1-L4). Their coordination chemistry has been studied/investigated with Zn(II) and Al(III). Alkane elimination route between the phenol-amidine proligands (L1H-L4H) and Et2Zn led to dinuclear complexes [(L1-L4)ZnEt]2 (1a-4a) in which the Zn centers are chelated by phenoxyamidine ligands and bridged through the oxygen atom of the phenoxy groups. Salt metathesis reaction between two equivalents of the sodium amidine phenate L1Na and ZnCl2 led to a bis-chelate chiral spiro-complex (L12Zn) 1a'. Analogous alkane eliminatio…

STRUCTURAL-CHARACTERIZATIONchemistry.chemical_elementCATALYSTSZinc010402 general chemistryLIGANDS SYNTHESIS01 natural sciencesRing-opening polymerizationCoordination complexCatalysisInorganic Chemistrychemistry.chemical_compoundZINCIMINE LIGANDSGroup (periodic table)Polymer chemistry[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryMethyleneCYCLIC ESTERSALUMINUM COMPLEXESchemistry.chemical_classificationEPSILON-CAPROLACTONELactide010405 organic chemistryOrganic ChemistryGROUP-4 METAL-COMPLEXES[CHIM.CATA]Chemical Sciences/CatalysisImine ligands0104 chemical scienceschemistryINITIATORSGROUP-4 METAL-COMPLEXES; ALUMINUM COMPLEXES; EPSILON-CAPROLACTONE; LIGANDS SYNTHESIS; IMINE LIGANDS; STRUCTURAL-CHARACTERIZATION; CYCLIC ESTERS; ZINC; CATALYSTS; INITIATORS
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A Route toward (Aminomethyl)cyclopentadienide Ligands and Their Group 4 Metal Complexes

2018

International audience

Zirconium010405 organic chemistryChemistrychemistry.chemical_element010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic ChemistryMetalGroup (periodic table)visual_artPolymer chemistryvisual_art.visual_art_medium[CHIM.COOR]Chemical Sciences/Coordination chemistryComputingMilieux_MISCELLANEOUSTitanium
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Hydrogen: a good partner for rhodium-catalyzed hydrosilylation

2014

The influence of hydrogen pressure on the hydrosilylation of ketones catalyzed by [((S)-SYNPHOS)Rh(nbd)]OTf has been studied. We have notably demonstrated that hydrogen significantly affected the outcome of the reaction while not being consumed as stoichiometric reducing agent. In THF, diethyl ether or toluene, the hydrogen pressure exceedingly accelerated the hydrosilylation reaction and preserved or even improved the enantioselectivity of the process. In CH2Cl2, the rhodium catalyst also showed generally higher catalytic activity under hydrogen pressure. Most serendipitously, several ketones were found to give products of absolute opposite configuration upon performing the hydrosilylation…

HydrogenHydrosilylationReducing agentEnantioselective synthesischemistry.chemical_elementGeneral ChemistryMedicinal chemistryRhodiumCatalysisInorganic Chemistrychemistry.chemical_compoundchemistryDiethyl etherStoichiometryApplied Organometallic Chemistry
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Amino-phosphanes in Rh(I)-catalyzed hydroformylation: new mechanistic insights using D2O as deuterium-labeling agent

2005

International audience; In previous work, we have demonstrated that the dangling amino group in amino-phosphane ligands increases the rate of Rh-catalyzed styrene hydroformylation as a function of the amino group basicity and of the distance between the P and N functions. We now report additional stereochemical and mechanistic insights resulting from new catalytic experiments performed with Rh-α-P,N catalytic systems in the presence of D2O. In addition to the expected D0 product, the formation of the β-D1 aldehyde, PhCH(CH2D)CHO was observed in all cases by 1H and 13C NMR spectroscopy, indicating that H/D exchange occurs for the rhodium-hydride complex. Minor amounts of a β-D2 product, PhCH…

Amino-phosphane ligandsStereochemistryEnantioselectivity010402 general chemistry01 natural sciencesAldehydeInorganic Chemistry[ CHIM.CATA ] Chemical Sciences/CatalysisDeprotonationMoietyRhodium[CHIM.COOR]Chemical Sciences/Coordination chemistryComputingMilieux_MISCELLANEOUSchemistry.chemical_classification010405 organic chemistryLigand[CHIM.ORGA]Chemical Sciences/Organic chemistryHydroformylation catalysis[ CHIM.COOR ] Chemical Sciences/Coordination chemistry[CHIM.CATA]Chemical Sciences/CatalysisAsymmetric induction0104 chemical sciencesEnantiopure drugchemistryH/D isotopic exchangeProtonolysisHydroformylation
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Synthetic Endeavors toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and Steric Properties

2015

A new family of cationic Ti complexes 4′ with a pendant phosphine of general formula [CpCpPTiOAr][BPh4] (Cp = η5-C5H5; CpP = η5-C5H4(CMe2)PR2) has been prepared in four steps from 6,6-dimethylfulvene. These complexes were designed to behave as Ti based frustrated Lewis pairs (FLPs). The key synthetic step is a reduction–oxidation sequence from [CpCpPTiClOAr] complexes 3 using lithium phosphide salts as the reductants and ferricinium tetraphenylborate as the oxidant. Four complexes have been structurally characterized by X-ray diffraction and show elongated Ti–P bonds, above 2.60 A. One complex (4b′: OAr = 2,6-Me2C6H3; PR2 = PCy2) reacted with benzaldehyde to form a typical FLP activation pr…

Steric effectsTetraphenylboratePhosphideStereochemistryOrganic ChemistryCationic polymerizationFrustrated Lewis pairInorganic ChemistryBenzaldehydechemistry.chemical_compoundchemistryPolymer chemistryPhosphoniumPhysical and Theoretical ChemistryPhosphineOrganometallics
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The Taming of Redox‐Labile Phosphidotitanocene Cations

2019

International audience; Tame d0 phosphidotitanocene cations stabilized with a pendant tertiary phosphane arm are reported. These compounds were obtained by one-electron oxidation of d1 precursors with [Cp2Fe][BPh4]. The electronic structure of these compounds was studied experimentally (EPR, UV/Vis, and NMR spectroscopy, X-ray diffraction analysis) and through DFT calculations. The theoretical analysis of the bonding situation by using the electron localization function (ELF) shows the presence of π-interactions between the phosphido ligand and Ti in the d0 complexes, whereas dπ–pπ repulsion prevents such interactions in the d1 complexes. In addition, CH–π interactions were observed in seve…

010402 general chemistry01 natural sciencesRedoxTransition metal phosphidesCatalysisFrustrated Lewis pairlaw.inventionchemistry.chemical_compoundFrustrated Lewis Pair (FLP)[CHIM.ANAL]Chemical Sciences/Analytical chemistrylaw[CHIM.COOR]Chemical Sciences/Coordination chemistryPhosphorus LigandsElectron paramagnetic resonanceDiphenylacetyleneComputingMilieux_MISCELLANEOUSTitanium[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryLigandOrganic Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryGeneral ChemistryNuclear magnetic resonance spectroscopyElectron localization function0104 chemical sciencesHomolysis[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryDensity Functional Theory (DFT)Crystallographychemistry[CHIM.CHEM]Chemical Sciences/CheminformaticsChemistry – A European Journal
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Cover Feature: A Route toward (Aminomethyl)cyclopentadienide Ligands and Their Group 4 Metal Complexes (Eur. J. Inorg. Chem. 34/2018)

2018

Inorganic ChemistryMetalFeature (computer vision)ChemistryStereochemistryGroup (periodic table)visual_artvisual_art.visual_art_mediumCover (algebra)European Journal of Inorganic Chemistry
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Highly antiproliferative neutral Ru(ii)-arene phosphine complexes

2018

Six ruthenium(II)- and four gold(I)-phosphine based complexes were synthesized and fully characterized. Some of them displayed strong antiproliferative properties for several types of cancer including colon, breast, and lung. Notably, two of the Ru(II) complexes displayed an IC50 of around 2 μM, which is exceptional for these types of complexes. The dramatic impact of the nature of the arene coordinated on the ruthenium center was clearly evidenced.

010405 organic chemistrychemistry.chemical_elementCancerGeneral Chemistry010402 general chemistrymedicine.disease01 natural sciencesMedicinal chemistryCatalysis0104 chemical sciencesRutheniumchemistry.chemical_compoundchemistryMaterials ChemistrymedicinePhosphineNew Journal of Chemistry
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CCDC 1868748: Experimental Crystal Structure Determination

2019

Related Article: Florian Chotard, Rosita Lapenta, Anaëlle Bolley, Audrey Trommenschlager, Cédric Balan, Jérôme Bayardon, Raluca Malacea-Kabbara, Quentin Bonnin, Ewen Bodio, Hélène Cattey, Philippe Richard, Stefano Milione, Alfonso Grassi, Samuel Dagorne, Pierre Le Gendre|2019|Organometallics|38|4147|doi:10.1021/acs.organomet.9b00501

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(2-({[(dimethylamino)(phenyl)methylidene]amino}methyl)phenolato)-zinc(ii)Experimental 3D Coordinates
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CCDC 1871410: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iv) tetraphenylborateExperimental 3D Coordinates
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CCDC 1578513: Experimental Crystal Structure Determination

2018

Related Article: Florian Chotard, Raluca Malacea-Kabbara, Cédric Balan, Ewen Bodio, Michel Picquet, Philippe Richard, Miguel Ponce-Vargas, Paul Fleurat-Lessard, Pierre Le Gendre|2018|Organometallics|37|812|doi:10.1021/acs.organomet.7b00851

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesdichloro-(cycloheptyl(diphenyl)phosphane)-(1-methyl-4-(propan-2-yl)benzene)-ruthenium(ii)
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CCDC 987356: Experimental Crystal Structure Determination

2014

Related Article: Adrien T. Normand, Alexandre Massard, Philippe Richard, Coline Canovas, Cédric Balan, Michel Picquet, Audrey Auffrant, Pierre Le Gendre|2014|Dalton Trans.|43|15098|doi:10.1039/C4DT00746H

Space GroupCrystallographyCrystal System(28-dimethyl-4466-tetraphenyl-37-diaza-46-diphosphanona-36-dien-5-yl)-(tetrahydrofuran)-lithiumCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871415: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(diphenylphosphanyl)-(diphenylphosphine)-titanium(iv) tetrakis(pentafluorophenyl)borateExperimental 3D Coordinates
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CCDC 1871416: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iv) tetraphenylborate tetrahydrofuran solvateExperimental 3D Coordinates
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CCDC 1578514: Experimental Crystal Structure Determination

2018

Related Article: Florian Chotard, Raluca Malacea-Kabbara, Cédric Balan, Ewen Bodio, Michel Picquet, Philippe Richard, Miguel Ponce-Vargas, Paul Fleurat-Lessard, Pierre Le Gendre|2018|Organometallics|37|812|doi:10.1021/acs.organomet.7b00851

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-((cyclohepta-35-dien-1-yl)(diphenyl)phosphane)-(1-methyl-4-(propan-2-yl)benzene)-ruthenium(ii)Experimental 3D Coordinates
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CCDC 1871408: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal System(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825467: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographyCrystal SystemCrystal Structuretrichloro-((2266-tetramethylpiperidinylmethyl)-cyclopentadienyl)-titaniumCell ParametersExperimental 3D Coordinates
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CCDC 1053357: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal Structure(1-((2-(bis(2-methylphenyl)phosphino)-1-methyl)ethyl)cyclopentadienyl)-(cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborateCell ParametersExperimental 3D Coordinates
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CCDC 1825466: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographydichloro-bis((dibenzylamino)-cyclopentadienyl)-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1868745: Experimental Crystal Structure Determination

2019

Related Article: Florian Chotard, Rosita Lapenta, Anaëlle Bolley, Audrey Trommenschlager, Cédric Balan, Jérôme Bayardon, Raluca Malacea-Kabbara, Quentin Bonnin, Ewen Bodio, Hélène Cattey, Philippe Richard, Stefano Milione, Alfonso Grassi, Samuel Dagorne, Pierre Le Gendre|2019|Organometallics|38|4147|doi:10.1021/acs.organomet.9b00501

Space GroupCrystallography2-({[phenyl(pyrrolidin-1-yl)methylidene]amino}methyl)phenolCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825460: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

dichloro-cyclopentadienyl-((2266-tetramethylpiperidinylmethyl)-cyclopentadienyl)-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1868749: Experimental Crystal Structure Determination

2019

Related Article: Florian Chotard, Rosita Lapenta, Anaëlle Bolley, Audrey Trommenschlager, Cédric Balan, Jérôme Bayardon, Raluca Malacea-Kabbara, Quentin Bonnin, Ewen Bodio, Hélène Cattey, Philippe Richard, Stefano Milione, Alfonso Grassi, Samuel Dagorne, Pierre Le Gendre|2019|Organometallics|38|4147|doi:10.1021/acs.organomet.9b00501

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-({[(dimethylamino)(phenyl)methylidene]amino}methyl)phenolato)-bis(methyl)-aluminium(iii)Experimental 3D Coordinates
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CCDC 1052598: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallography(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-titanium tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825463: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographydichloro-cyclopentadienyl-((di-isopropylammoniomethyl)-cyclopentadienyl)-titanium chlorideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052596: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(eta5-cyclopentadienyl)-phenolato-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-titanium tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 987359: Experimental Crystal Structure Determination

2014

Related Article: Adrien T. Normand, Alexandre Massard, Philippe Richard, Coline Canovas, Cédric Balan, Michel Picquet, Audrey Auffrant, Pierre Le Gendre|2014|Dalton Trans.|43|15098|doi:10.1039/C4DT00746H

Space GroupCrystallographyCrystal System(t-butylimino)-chloro-(2288-tetramethyl-4466-tetraphenyl-37-diaza-46-diphosphanona-36-dien-5-yl)-titanium(iv) unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871418: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(3-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-diphenylphosphanyl-(eta5-cyclopentadienyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1871412: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(2-(dicyclohexylphosphanyl)-12-diphenylethenyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1825459: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-((dibenzylaminomethyl)-cyclopentadienyl)-cyclopentadienyl-titaniumExperimental 3D Coordinates
researchProduct

CCDC 1052597: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1871414: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographybis(eta5-cyclopentadienyl)-bis(tetrahydrofuran)-titanium(iii) tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1052593: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-phenolato-chloro-titaniumExperimental 3D Coordinates
researchProduct

CCDC 1578510: Experimental Crystal Structure Determination

2018

Related Article: Florian Chotard, Raluca Malacea-Kabbara, Cédric Balan, Ewen Bodio, Michel Picquet, Philippe Richard, Miguel Ponce-Vargas, Paul Fleurat-Lessard, Pierre Le Gendre|2018|Organometallics|37|812|doi:10.1021/acs.organomet.7b00851

Space GroupCrystallographyCrystal SystemCrystal Structuretris(mu-chloro)-bis((cyclohepta-35-dien-1-yl)(diphenyl)phosphane)-di-ruthenium chloride chloroform solvateCell ParametersExperimental 3D Coordinates
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CCDC 1868747: Experimental Crystal Structure Determination

2019

Related Article: Florian Chotard, Rosita Lapenta, Anaëlle Bolley, Audrey Trommenschlager, Cédric Balan, Jérôme Bayardon, Raluca Malacea-Kabbara, Quentin Bonnin, Ewen Bodio, Hélène Cattey, Philippe Richard, Stefano Milione, Alfonso Grassi, Samuel Dagorne, Pierre Le Gendre|2019|Organometallics|38|4147|doi:10.1021/acs.organomet.9b00501

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-2-({[phenyl(pyrrolidin-1-yl)methylidene]amino}methyl)phenolato)-bis(ethyl)-di-zinc(ii)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1053358: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(cyclopentadienyl)-([dicyclohexyl(2-cyclopentadienylpropan-2-yl)phosphaniumyl](phenyl)methoxy)-(26-dimethylphenolato)-titanium tetraphenylborate tetrahydrofuran solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825465: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

dichloro-bis((dibenzylaminomethyl)-cyclopentadienyl)-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 987357: Experimental Crystal Structure Determination

2014

Related Article: Adrien T. Normand, Alexandre Massard, Philippe Richard, Coline Canovas, Cédric Balan, Michel Picquet, Audrey Auffrant, Pierre Le Gendre|2014|Dalton Trans.|43|15098|doi:10.1039/C4DT00746H

Space GroupCrystallographyCrystal SystemCrystal Structure(tetrahydrofuran)-(2288-tetramethyl-4466-tetraphenyl-37-diaza-46-diphosphanona-36-dien-5-yl)-lithiumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1937786: Experimental Crystal Structure Determination

2019

Related Article: Florian Chotard, Rosita Lapenta, Anaëlle Bolley, Audrey Trommenschlager, Cédric Balan, Jérôme Bayardon, Raluca Malacea-Kabbara, Quentin Bonnin, Ewen Bodio, Hélène Cattey, Philippe Richard, Stefano Milione, Alfonso Grassi, Samuel Dagorne, Pierre Le Gendre|2019|Organometallics|38|4147|doi:10.1021/acs.organomet.9b00501

Space GroupCrystallographybis(mu-isopropoxo)-bis(N'-[(2-oxyphenyl)methyl]-NN-dimethylbenzenecarboximidamide)-di-zincCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871411: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

bis(eta5-cyclopentadienyl)-(2-(dicyclohexylphosphanyl)-12-diphenylethenyl)-titanium(iv) tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1578511: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-(cycloheptyl(diphenyl)phosphane)-(methylbenzene)-ruthenium(ii) toluene solvateExperimental 3D Coordinates
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CCDC 1052592: Experimental Crystal Structure Determination

2015

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(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-dimethyl-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 987358: Experimental Crystal Structure Determination

2014

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Space GroupCrystallography(bis(NPP-triphenylphosphorimidoyl)methyl)-chloro-(t-butylimino)-titanium(iv)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871409: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal Structure(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Cell ParametersExperimental 3D Coordinates
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CCDC 1578512: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal Structuredichloro-(cycloheptyl(diphenyl)phosphane)-(ethyl benzoate)-ruthenium(ii)Cell ParametersExperimental 3D Coordinates
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CCDC 1052595: Experimental Crystal Structure Determination

2015

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Space GroupCrystallography(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-(eta5-cyclopentadienyl)-chloro-titaniumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052594: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-chloro-(26-dimethylphenolato)-titaniumExperimental 3D Coordinates
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CCDC 1825462: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-cyclopentadienyl-((pyrrolidinium-1-ylmethyl)-cyclopentadienyl)-titanium chloride chloroform solvateExperimental 3D Coordinates
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CCDC 1871417: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(dicyclohexylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1825461: Experimental Crystal Structure Determination

2018

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dichloro-cyclopentadienyl-((2266-tetramethylpiperidinylmethyl)-cyclopentadienyl)-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825458: Experimental Crystal Structure Determination

2018

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dichloro-((di-isopropylaminomethyl)-cyclopentadienyl)-(pentamethyl-cyclopentadienyl)-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1868750: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systemdimethyl-[2-({[phenyl(pyrrolidin-1-yl)methylidene]amino}methyl)phenolato]-aluminium(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825464: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesdichloro-cyclopentadienyl-((2266-tetramethylpiperidiniomethyl)-cyclopentadienyl)-titanium chloride
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CCDC 1868746: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-2-({[(dimethylamino)(phenyl)methylidene]amino}methyl)phenolato)-bis(ethyl)-di-zinc(ii)Experimental 3D Coordinates
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CCDC 1868743: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureN-[(2-hydroxyphenyl)methyl]-N'N'-dimethylbenzenecarboximidamidium bromideCell ParametersExperimental 3D Coordinates
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CCDC 1578509: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systemdichloro-((cyclohepta-35-dien-1-yl)(diphenyl)phosphane)-(ethyl benzoate)-ruthenium(ii) toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871413: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-{[ferrocenyl(oxido)methyl](dicyclohexyl)phosphaniumyl}-12-diphenylethenyl)-bis(eta5-pentamethylcyclopentadienyl)-titanium(iv) tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
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