0000000000524159
AUTHOR
Niclas Schupp
Electrochemical synthesis of carbazoles by dehydrogenative coupling reaction
Abstract A constant current protocol, employing undivided cells, a remarkably low supporting electrolyte concentration, inexpensive electrode materials, and a straightforward precursor synthesis enabling a novel access to N‐protected carbazoles by anodic N,C bond formation using directly generated amidyl radicals is reported. Scalability of the reaction is demonstrated and an easy deblocking of the benzoyl protecting group is presented.
CCDC 1986341: Experimental Crystal Structure Determination
Related Article: Anton Kehl, Niclas Schupp, Valentina M. Breising, Dieter Schollmeyer, Siegfried R. Waldvogel|2020|Chem.-Eur.J.|26|15847|doi:10.1002/chem.202003430