Valorización de residuos con cromo del sector galvánico para su utilización como licor curtiente

El presente trabajo desarrolla la metodología necesaria para el acondicionamiento y valorización de los baños agotados de Cr (VI), provenientes de la industria galvánica, para su utilización como licor curtiente en el sector de curtición.

Precision experiments with time-resolved Schottky mass spectrometry

Abstract A large area on the mass surface of neutron-deficient nuclides (36≤Z≤85) was measured with time-resolved Schottky mass spectrometry at the FRS-ESR facilities. The masses of 114 nuclides were obtained for the first time from which 43 were determined via known decay energies. The improved mass accuracy of 30 keV allowed to study the isospin dependence of nuclear pairing, to precisely locate the one-proton dripline for odd-Z isotopes from Tb to Pa and to make crucial tests of the predictive powers of modern mass models.

Mass measurement of cooled neutron-deficient bismuth projectile fragments with time-resolved Schottky mass spectrometry at the FRS-ESR facility

Masses of 582 neutron-deficient nuclides ($30\leq{Z}\leq{85}$) were measured with time-resolved Schottky mass spectrometry at the FRS-ESR facility at GSI, 117 were used for calibration. The masses of 71 nuclides were obtained for the first time. A typical mass accuracy of 30 $\mu$u was achieved. These data have entered the latest atomic mass evaluation. The mass determination of about 140 additional nuclides was possible via known energies ($Q$-values) of $\alpha-$, $\beta-$, or proton decays. The obtained results are compared with the results of other measurements.

Status and perspectives of atomic physics research at GSI

A short overview on the results of atomic physics research at the storage ring ESR is given followed by a presentation of the envisioned atomic physics program at the planned new GSI facility. The proposed new GSI facility will provide highest intensities of relativistic beams of both stable and unstable heavy nuclei - up to a Lorentz factor of 24. At those relativistic velocities, the energies of optical transitions, such as for lasers.. are boosted into the X-ray region and the high-charge state ions generate electric and magnetic fields of exceptional strength. Together with high beam intensities a range of important experiments can be anticipated, for example electronic transitions in r…

Observation of a dramatic hindrance of the nuclear decay of isomeric states for fully ionized atoms

Abstract The half-lives of isomeric states of fully ionized 144Tb, 149Dy and 151Er have been measured. These nuclides were produced via fragmentation of about 900 MeV/u 209Bi projectiles, separated in flight with the fragment separator (FRS) and stored in the cooler ring (ESR). The decay times of the cooled fragments have been measured with time-resolved Schottky spectrometry. We observed for the first time drastic increases of the half-lives of bare isomers by factors of up to 30 compared to their neutral counterparts. This is due to the exclusion of the strong internal conversion and electron-capture channels in the radioactive decay of these bare nuclei. The experimental results are in g…

Incorporación de elementos traza en conchas de melanopsis durante el crecimiento : posibilidades de aplicación en paleoecología

El objetivo del presente trabajo está encaminado al estudio de las variaciones de oligoelementos en la concha de un gasterópodo de agua dulce del género Melanopsis (U dufouri (FERUSSAC), con dos morfotipos) y si éstas tienen que ver, o no, con la fluctuación de una serie de parámetros ambientales. La importancia del trabajo radica en la posibilidad de la aplicación paleoecológica de sus resultados, ya que el género MelanopsÍs tiene un abundante registro fósil durante todo el Cenozoico. La incorporación de oligoelementos se efectúa a medida que la concha va creciendo por acreción; lo ideal sería que tal crecimiento fuera circadiano, ya que se podría seguir día a día, sobre la concha, la fluc…

Laser-stimulated two-step recombination of highly charged ions and electrons in a storage ring

Two-step resonant laser-stimulated recombination of highly charged ions was performed for the first time. Nd:YAG laser pulses overlapped with an Ar[sup 18+] beam in the electron cooler of the ESR storage ring at GSI induced transitions from the continuum to the [ital n]=81 state of hydrogenlike Ar[sup 17+]. To avoid reionization in the bending magnet before reaching the detector, the [ital n]=81 population was transferred to a state well below the reionization threshold by a Ti:sapphire laser. Tuning of this laser yielded the [ital n]=81 to 36 and 37 transition-line profiles. The two-step method provides access to detailed Rydberg spectroscopy in an electron beam environment.

First isochronous mass spectrometry at the experimental storage ring ESR

Short-lived exotic nuclei can be produced and separated with the high-energy secondary nuclear beam facility FRS at GSI. These nuclides can be injected and stored in the storage ring ESR. The lower lifetime limit of the presently existing methods for mass measurements on these nuclides at the ESR is about a few seconds. We have developed and investigated an isochronous operational mode of the ESR, that makes mass measurements of nuclides with lifetimes down to a few ls feasible. It has been commissioned in experiments using long-lived nuclides with known masses. A mass resolving power of about 150 000 has been achieved in a "rst pilot experiment. A suitable detector system has been implemen…

Simultaneous Measurement ofβ−Decay to Bound and Continuum Electron States

We report the first measurement of a ratio {lambda}{sub {beta}{sub b}}/{lambda}{sub {beta}{sub c}} of bound-state ({lambda}{sub {beta}{sub b}}) and continuum-state ({lambda}{sub {beta}{sub c}}) {beta}{sup -}-decay rates for the case of bare {sup 207}Tl{sup 81+} ions. These ions were produced at the GSI fragment separator FRS by projectile fragmentation of a {sup 208}Pb beam. After in-flight separation with the B{rho}-{delta}E-B{rho} method, they were injected into the experimental storage-ring ESR at an energy of 400.5A MeV, stored, and electron cooled. The number of both the {sup 207}Tl{sup 81+} ions and their bound-state {beta}{sup -}-decay daughters, hydrogenlike {sup 207}Pb{sup 81+} ion…

New results with stored exotic nuclei at relativistic energies

Recently, much progress has been made with stored exotic nuclei at relativistic velocities ( v c = 0.7 ) . Fragments of 208Pb and 209Bi projectiles and fission products from 238U ions were produced, separated in flight with the fragment separator FRS, and injected into the storage-cooler ring ESR for precision measurements. 114 new masses of neutron-deficient isotopes in the lead region have been measured with time-resolved Schottky Mass Spectrometry (SMS). A new isospin dependence of the pairing energy was observed due to the improved mass accuracy of typically 1.5×10-7 (30 keV). New masses of short-lived neutron-rich fission fragments have been obtained with Isochronous Mass Spectrometry …

Study of Basic Nuclear Properties of Highly-Charged, Unstable Nuclei at the SIS-FRS-ESR Complex

Recent progress in experiments with exotic nuclear beams at the SIS-FRS-ESR facility is summarized. New results on gross properties of exotic nuclei like binding energy, half-lives, and decay modes are presented. A brief outlook to future experiments is given.

Mass mapping of a new area of neutron-deficient suburanium nuclides

Abstract The masses of 64 short-lived neutron-deficient nuclides covering the element range from tungsten to uranium have been obtained for the first time. They have been evaluated by combining directly measured masses from Schottky mass spectrometry with linked experimental Q-values in α-decay chains. Based on these new mass data we have determined the one-proton and two-proton drip-lines as well as the size of the “littoral shallow” of the sea of instability. No evidence of a Thomas–Ehrman shift has been found in the region of the investigated heavy nuclides. A peculiar behavior of two-proton separation energies has been observed in the lead region. The predictive power of various mass mo…

The living freshwater gastropod Melanopsis dufouri (FERUSSAC) has two morphotypes. The study of chemical variation of trace-elements in this gastropod and its correlation with the environmental fluctuation are the aim of this paper. Due to the genus Melanopsis has an abundant fossil record during the Cenozoic, the results of the present work could be of paleoecological interest. Trace-elements are embodied in the shell during growth. The shell of M. dufouri has accretionary growth. There are several examples cited on circadian accretionary growth in invertebrate shells. However, in the present case and as a first conclusion, the accretion rate depends on the size of the shell. In a short-ti…

Experiments with stored exotic nuclei at relativistic energies

Abstract A review and recent progress are presented from experiments on masses and lifetimes of bare and few-electron exotic nuclei at GSI. Relativistic rare isotopes produced via projectile fragmentation and fission were separated in flight by the fragment separator FRS and injected into the storage ring ESR. This worldwide unique experimental method gives access to all fragments with half-lives down to the microsecond range. The great research potential is demonstrated by the discovery of new isotopes along with simultaneous mass and lifetime measurements. Single particle decay measurements and the continuous recording of both stored mother and daughter nuclei open up a new era for nuclea…

Schottky mass measurements of stored and cooled neutron-deficient projectile fragments in the element range of 57≤Z≤84

Abstract A novel method for direct, high precision mass measurements of relativistic exotic nuclei has been successfully applied in the storage ring ESR at GSI. The nuclei of interest were produced by projectile fragmentation of 930 MeV / u bismuth ions, separated in-flight by the fragment separator FRS, stored and cooled in the ESR. The mass values have been deduced from the revolution frequencies of the coasting cooled ions. We have measured 104 new mass values with a precision of about 100 keV and a resolving power of 3.5×10 5 for the neutron-deficient isotopes of the elements 57≤Z≤84 . This paper presents the experimental method, the mass evaluation and a table of the experimental mass …