0000000000548056
AUTHOR
Manish Kumar
Klimt artwork: red-pigment material investigation by backscattering Fe-57 Mössbauer spectroscopy, SEM and p-XRF
Material tests were performed on a rediscovered Klimt-artwork "Trompetender Putto". We performed studies on the red colored spots, mainly taken from non-restored parts. MIMOS II Fe-57 Mossbauer spectroscopy (novelty in art-pigment analysis) mainly reveals haematite and crystallized goethite in red colors. Electron microscopy can identify various layers of the original and overpainting of an artwork. The number of layers fluctuates between three and four chemically painted areas. The portable X-ray fluorescence analysis enables to reduce the pigment list to containing mercury (cinnabar), lead, zinc, iron and titanium. Infrared-light-irradiation visualizes the different age of the pigments.
An Efficient Immunization Strategy Using Overlapping Nodes and Its Neighborhoods
International audience; When an epidemic occurs, it is often impossible to vaccinate the entire population due to limited amount of resources. Therefore, it is of prime interest to identify the set of influential spreaders to immunize, in order to minimize both the cost of vaccine resource and the disease spreading. While various strategies based on the network topology have been introduced, few works consider the influence of the community structure in the epidemic spreading process. Nowadays, it is clear that many real-world networks exhibit an overlapping community structure, in which nodes are allowed to belong to more than one community. Previous work shows that the numbers of communit…
Acidic Co-Catalysts in Cationic Gold Catalysis.
A systematic study on the effects of Lewis or Bronsted acid co-catalysts in gold-catalyzed reactions was undertaken using representative reactions (O-, N-, and C-nucleophilic additions to alkynes). Through these reactions, it was demonstrated that an acidic co-catalyst can increase the catalyst turnover significantly, enabling practical reaction rates at competitive catalyst loadings (<1 mol %). Further investigation is currently underway to improve the understanding of the subtle principles underlying these experimental observations.