0000000000559190
AUTHOR
Aurelian Rotaru
Room temperature hysteretic spin crossover in a new cyanoheterometallic framework.
A new iron(II)-based spin-crossover compound with thermal hysteresis operating under ambient conditions is reported. This complex exhibits a high reproducibility of the spin transition in many successive thermal cycles, stability of both spin states at room temperature and an attractive operational temperature range.
Pressure effect investigations on spin-crossover coordination compounds
International audience; The piezochromic properties of spin-crossover complexes have been recognized for a long time, with increasing pressure favouring the low spin state due to its smaller volume and therefore shifting the spin equilibrium towards higher temperatures and accelerating the relaxation at a given temperature. However, the interpretation and quantification of pressure-induced changes have been several times compromised by the relatively poor and incomplete spectral and structural information provided by the detection methods or due to the experimental difficulties related to the need for hydrostatic conditions at low temperatures. The present review is therefore primarily focu…
CCDC 1878182: Experimental Crystal Structure Determination
Related Article: Volodymyr M. Hiiuk, Sergiu Shova, Aurelian Rotaru, Vadim Ksenofontov, Igor O. Fritsky, Il'ya A. Gural'skiy|2019|Chem.Commun.|55|3359|doi:10.1039/C8CC10260K
CCDC 1878181: Experimental Crystal Structure Determination
Related Article: Volodymyr M. Hiiuk, Sergiu Shova, Aurelian Rotaru, Vadim Ksenofontov, Igor O. Fritsky, Il'ya A. Gural'skiy|2019|Chem.Commun.|55|3359|doi:10.1039/C8CC10260K