0000000000563235

AUTHOR

G. Asensio

showing 35 related works from this author

From over-stoichiometric to sub-stoichiometric enantioselective protonation with 2-sulfinyl alcohols: A view in perspective

2005

A general study of the enantioselective protonation of prochiral enolates with 2-sulfinyl alcohols is reported. The modification of reaction conditions to reduce drastically the amount of chiral proton source needed to obtain a good enantiomeric excess is reported. The effects of the different factors controlling the stereoselectivity are clearly established. Different protocols for enolate generation are compared. Medio Simon, Mercedes, Mercedes.Medio@uv.es ; Aleman Lopez, Pedro Antonio, Pedro.Aleman@uv.es ; Gil Tomas, Jesus Javier, Jesus.J.Gil@uv.es ; Asensio, Aguilar Gregorio, Gregorio.Asensio@uv.es

Enantioselective protonationUNESCO::QUÍMICA:QUÍMICA::Química orgánica [UNESCO]Sulfinyl alcoholsEnolatesEnolates ; Enantioselective protonation ; Sulfinyl alcoholsUNESCO::QUÍMICA::Química orgánica:QUÍMICA [UNESCO]
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CCDC 153862: Experimental Crystal Structure Determination

2001

Related Article: G.Asensio, P.Gavina, A.Cuenca, M.C.R.de Arellano, L.R.Domingo, M.Medio-Simon|2000|Tetrahedron:Asymm.|11|3481|doi:10.1016/S0957-4166(00)00330-X

(SRs)-1-(4-Methylphenylsulfinyl)-2-propanethiolSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 800581: Experimental Crystal Structure Determination

2011

Related Article: A.Gimeno, M.Medio-Simon, C.R.de Arellano, G.Asensio, A.B.Cuenca|2010|Org.Lett.|12|1900|doi:10.1021/ol100595s

Space GroupCrystallographyCrystal System4-Methylene-3-phenyl-34-dihydroquinazolin-2(1H)-oneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 801116: Experimental Crystal Structure Determination

2011

Related Article: G.Asensio, A.B.Cuenca, M.A.Esteruelas, M.Medio-Simon, M.Olivan, M.Valencia|2010|Inorg.Chem.|49|8665|doi:10.1021/ic101498h

Space GroupCrystallographyCrystal SystemCrystal StructureTrichloro(-(99-dimethyl-9H-xanthene-45-diyl)bis(diisopropylphosphine))-osmiumCell ParametersExperimental 3D Coordinates
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CCDC 800582: Experimental Crystal Structure Determination

2011

Related Article: A.Gimeno, M.Medio-Simon, C.R.de Arellano, G.Asensio, A.B.Cuenca|2010|Org.Lett.|12|1900|doi:10.1021/ol100595s

Space GroupCrystallographyN2-Diphenyl-1H-indole-1-carboxamideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 288794: Experimental Crystal Structure Determination

2006

Related Article: M.E.Gonzalez-Nunez, J.Royo, R.Mello, M.Baguena, J.M.Ferrer, C.R.de Arellano, G.Asensio, G.K.S.Prakash|2005|J.Org.Chem.|70|7919|doi:10.1021/jo0509511

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(Z)-2-(5-Hydroxyadamantyl)methylketone
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CCDC 601636: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

(SR~S~)-3-Fluoro-2-hydroxypropyl p-tolyl sulfoxideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 616336: Experimental Crystal Structure Determination

2007

Related Article: N.Rodriguez, C.R.de Arellano, G.Asensio, M.Medio-Simon|2007|Chem.-Eur.J.|13|4223|doi:10.1002/chem.200601488

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(R)-1-(1-Bromoethylsulfonyl)-4-methylbenzeneExperimental 3D Coordinates
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CCDC 601642: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(RR~S~)-3-Fluoro-2-hydroxypropyl p-tolyl sulfoxideExperimental 3D Coordinates
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CCDC 866169: Experimental Crystal Structure Determination

2012

Related Article: C.Andreu, F.Sanz, G.Asensio|2012|Eur.J.Org.Chem.|2012|4185|doi:10.1002/ejoc.201200430

bis(L-Prolinamide)-chloro-zinc(ii) chlorideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 601638: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal Structure(SR~S~)-333-Trifluoro-2-hydroxypropyl p-tolyl sulfoxideCell ParametersExperimental 3D Coordinates
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CCDC 601637: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(SR~S~)-33-Difluoro-2-hydroxypropyl p-tolyl sulfoxideExperimental 3D Coordinates
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CCDC 601645: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(RR~S~)-333-Trifluoro-2-hydroxypropyl p-tolyl sulfoxideExperimental 3D Coordinates
researchProduct

CCDC 601641: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

(SR~S~)-3-Methyl-2-hydroxybutyl p-tolyl sulfoxideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 288792: Experimental Crystal Structure Determination

2006

Related Article: M.E.Gonzalez-Nunez, J.Royo, R.Mello, M.Baguena, J.M.Ferrer, C.R.de Arellano, G.Asensio, G.K.S.Prakash|2005|J.Org.Chem.|70|7919|doi:10.1021/jo0509511

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(E)-5-Hydroxy-2-adamantyl methylsulfonate
researchProduct

CCDC 288796: Experimental Crystal Structure Determination

2006

Related Article: M.E.Gonzalez-Nunez, J.Royo, R.Mello, M.Baguena, J.M.Ferrer, C.R.de Arellano, G.Asensio, G.K.S.Prakash|2005|J.Org.Chem.|70|7919|doi:10.1021/jo0509511

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(Z)-(5-Hydroxy-2-adamantyl)methylsulfoneExperimental 3D Coordinates
researchProduct

CCDC 801114: Experimental Crystal Structure Determination

2011

Related Article: G.Asensio, A.B.Cuenca, M.A.Esteruelas, M.Medio-Simon, M.Olivan, M.Valencia|2010|Inorg.Chem.|49|8665|doi:10.1021/ic101498h

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesDibenzo[bd]furan-46-diylbis(diisopropylphosphine)
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CCDC 288793: Experimental Crystal Structure Determination

2006

Related Article: M.E.Gonzalez-Nunez, J.Royo, R.Mello, M.Baguena, J.M.Ferrer, C.R.de Arellano, G.Asensio, G.K.S.Prakash|2005|J.Org.Chem.|70|7919|doi:10.1021/jo0509511

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(Z)-5-Hydroxy-2-adamantyl methylsulfonate
researchProduct

CCDC 616337: Experimental Crystal Structure Determination

2007

Related Article: N.Rodriguez, C.R.de Arellano, G.Asensio, M.Medio-Simon|2007|Chem.-Eur.J.|13|4223|doi:10.1002/chem.200601488

Space GroupCrystallographyCrystal SystemCrystal Structurebis(Triphenylphosphine)-di-bromo-palladium(ii) dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 153864: Experimental Crystal Structure Determination

2001

Related Article: G.Asensio, P.Gavina, A.Cuenca, M.C.R.de Arellano, L.R.Domingo, M.Medio-Simon|2000|Tetrahedron:Asymm.|11|3481|doi:10.1016/S0957-4166(00)00330-X

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(SRs)-1-(4-Methylphenylsulfinylmethyl)propyl ethanethioateExperimental 3D Coordinates
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CCDC 212082: Experimental Crystal Structure Determination

2003

Related Article: N.Rodriguez, A.Cuenca, C.Ramirez de Arellano, M.Medio-Simon, G.Asensio|2003|Org.Lett.|5|1705|doi:10.1021/ol034358m

Space GroupCrystallographyBromo-(phenylsulfinylmethyl)-bis(triphenylphosphine)-palladium dideuterodichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 616335: Experimental Crystal Structure Determination

2007

Related Article: N.Rodriguez, C.R.de Arellano, G.Asensio, M.Medio-Simon|2007|Chem.-Eur.J.|13|4223|doi:10.1002/chem.200601488

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(S~s~R)-1-Methyl-4-(1-phenylethylsulfinyl)benzeneExperimental 3D Coordinates
researchProduct

CCDC 601643: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(RR~S~)-33-Difluoro-2-hydroxypropyl p-tolyl sulfoxideExperimental 3D Coordinates
researchProduct

CCDC 866170: Experimental Crystal Structure Determination

2012

Related Article: C.Andreu, F.Sanz, G.Asensio|2012|Eur.J.Org.Chem.|2012|4185|doi:10.1002/ejoc.201200430

Space GroupCrystallographybis(L-Prolinamide)-bromo-zinc(ii) bromideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 801117: Experimental Crystal Structure Determination

2011

Related Article: G.Asensio, A.B.Cuenca, M.A.Esteruelas, M.Medio-Simon, M.Olivan, M.Valencia|2010|Inorg.Chem.|49|8665|doi:10.1021/ic101498h

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersTrichloro-((99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-osmium diethyl ether solvateExperimental 3D Coordinates
researchProduct

CCDC 601646: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(RR~S~)-3-Methyl-2-hydroxybutyl p-tolyl sulfoxideExperimental 3D Coordinates
researchProduct

CCDC 153863: Experimental Crystal Structure Determination

2001

Related Article: G.Asensio, P.Gavina, A.Cuenca, M.C.R.de Arellano, L.R.Domingo, M.Medio-Simon|2000|Tetrahedron:Asymm.|11|3481|doi:10.1016/S0957-4166(00)00330-X

(SRs)-3-Methyl-1-(4-methylphenylsulfinyl)-2-butanethiolSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 288795: Experimental Crystal Structure Determination

2006

Related Article: M.E.Gonzalez-Nunez, J.Royo, R.Mello, M.Baguena, J.M.Ferrer, C.R.de Arellano, G.Asensio, G.K.S.Prakash|2005|J.Org.Chem.|70|7919|doi:10.1021/jo0509511

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(E)-(5-Hydroxy-2-adamantyl)methylsulfoneExperimental 3D Coordinates
researchProduct

CCDC 801115: Experimental Crystal Structure Determination

2011

Related Article: G.Asensio, A.B.Cuenca, M.A.Esteruelas, M.Medio-Simon, M.Olivan, M.Valencia|2010|Inorg.Chem.|49|8665|doi:10.1021/ic101498h

Space GroupCrystallographyCrystal SystemTrichloro-((dibenzo[bd]furan-46-diyl)bis(diisopropylphosphine))-osmium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 601639: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(SR~S~)-3-Chloro-33-difluoro-2-hydroxypropyl p-tolyl sulfoxideExperimental 3D Coordinates
researchProduct

CCDC 866168: Experimental Crystal Structure Determination

2012

Related Article: C.Andreu, F.Sanz, G.Asensio|2012|Eur.J.Org.Chem.|2012|4185|doi:10.1002/ejoc.201200430

Space GroupCrystallographybis(L-Prolinamide)-acetato-zinc(ii) tetraacetato-zinc(ii) trihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 938143: Experimental Crystal Structure Determination

2013

Related Article: T. Varea, A. Alcalde, C. López de Dicastillo, C.Ramírez de Arellano, F. P. Cossío, G. Asensio|2012|J.Org.Chem.|77|6327|doi:10.1021/jo300806y

Space GroupCrystallography2-Hydroxy-34-diisopropoxy-5-methyl-4-vinylcyclopent-2-en-1-oneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 601644: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(RR~S~)-333-Trifluoro-2-hydroxypropyl p-tolyl sulfoxideExperimental 3D Coordinates
researchProduct

CCDC 288791: Experimental Crystal Structure Determination

2006

Related Article: M.E.Gonzalez-Nunez, J.Royo, R.Mello, M.Baguena, J.M.Ferrer, C.R.de Arellano, G.Asensio, G.K.S.Prakash|2005|J.Org.Chem.|70|7919|doi:10.1021/jo0509511

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(Z)-4-Chloro-1-adamantanolExperimental 3D Coordinates
researchProduct

CCDC 601640: Experimental Crystal Structure Determination

2007

Related Article: G.Asensio, M.Medio-Simon, P.Aleman, C.R.de Arellano|2006|Cryst.Growth Des.|6|2769|doi:10.1021/cg060465m

Space GroupCrystallography(SR~S~)-333-Trichloro-2-hydroxypropyl p-tolyl sulfoxideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct