0000000000563633
AUTHOR
M. Jannin
Optical rotary power at the resonance of the terbium F-7(6)-> D-5(4) line in terbium gallium garnet
0038-1101; The Tb3+ absorption line F-7(6)-->D-5(4) Of the Terbium Gallium Garnet crystal is excited with an Argon ion laser. The Verdet's constant has been determined and reported against 1/lambda(2), showing no significant resonant behaviour at absorption resonance. The utility and the constraints of the crystal at this particular resonant wavelength are pointed out. (C) 1998 Elsevier Science Ltd. All rights reserved.
Evolution towards centrosymmetry of the nonlinear-optical materialRbTiOPO4in the temperature range 293–973 K: Alkaline displacements and titanyl deformations
The crystal structure of rubidium titanyl phosphate, ${\mathrm{RbTiOPO}}_{4}$ (space group ${\mathrm{Pna}2}_{1}$), has been refined at room temperature, and at 473, 673, 873, and 973 K, by using single-crystal x-ray-diffraction techniques. The data show a large anharmonic motion of the rubidium ions increasing with temperature. To describe the importance of this motion in the phase-transition procedure and in the ionic conductivity phenomenon, two models are developed. The study of the deviation to the centrosymmetric structure (space group Pnan) shows that the change towards centrosymmetry of the titanyl groups correlates directly with the observed variation of the second-harmonic generati…
Structural and Vibrational Study of a New Mixed Dipotassium Hydrogenselenate Dihydrogenphosphate K2(HSeO4)1.5 (H2PO4)0.5.
Abstract Ongoing studies of the KHSeO4–KH2PO4 system, aimed at developing novel proton conducting solids, resulted in the new compound K2(HSeO4)1.5(H2PO4)0.5 (dipotassium hydrogenselenate dihydrogenphosphate). The crystals have been prepared by slow evaporation of an aqueous solution at room temperature. The structural properties of the crystals were characterized by X-ray single analysis (performed at room temperature), which revealed that K2(HSeO4)1.5(H2PO4)0.5 (KHSeP) crystallizes in space group P 1 ¯ with lattice parameters: a = 7.417(3) A, b = 7.668(2) A, c = 7.744(5) A, α = 71.59(3)°, β = 87.71(4)° and γ = 86.04(6)°. The compound has a unit cell volume 416.8(3) A3 and two formula unit…
Optical rotary power at the resonance of the Terbium 7F6→5D4 line in Terbium Gallium Garnet
Abstract The Tb 3+ absorption line 7 F 6 → 5 D 4 of the Terbium Gallium Garnet crystal is excited with an Argon ion laser. The Verdet's constant has been determined and reported against 1/ λ 2 , showing no significant resonant behaviour at absorption resonance. The utility and the constraints of the crystal at this particular resonant wavelength are pointed out.
Order-disorder evolution in solid solutions of the NLO material KTiOPO : K Rb TiOPO and K Rb TiOPO in the temperature range 293-973 K
K0.88Rb0.12TiOPO4 and K0.465Rb0.535TiOPO4 solid solutions of the potassium titanyl phosphate (KTiOPO4, space group Pna21) family, are described at 293, 473, 673, 873 and at 973 K. Their high resolution structures are obtained by using accurate single-crystal X-ray diffraction techniques at high resolution, (sin A-1. Large anharmonic motion of alkaline ions increasing with temperature allows the evolution of the rubidium and potassium ions repartition in the two alkaline sites versus temperature. To describe this motion inducing ionic conductivity phenomenon and to determine accurately the order-disorder evolution, two alkaline site refinement models are developed and discussed. A thermodyna…
Behaviour of the non-linear optical material KTiOPO4in the temperature range 293-973 K studied by x-ray diffractometry at high resolution: alkaline displacements
The crystal structure of potassium titanyl phosphate, KTiOPO4 (space group Pna21), has been refined at room temperature, at 673 K, and at 973 K, by using accurate single-crystal x-ray diffraction techniques at high resolution (dmin = 0.35 A). The data show a large amount of anharmonic motion of the potassium ions, increasing with temperature. To describe this motion, two models are developed: a normal refinement including potassium anharmonic thermal displacement parameters, which describes the average motion of the alkaline sites, and another model in which the potassium sites are split within the harmonic approximation and the displacements of the potassium ions versus temperature are des…