0000000000590054
AUTHOR
M. Hirsimäki
Strong, Rapid and Reversible Photochromic Response of Nb doped TiO2 Nanocrystal Colloids in Hole Scavenging Media
Understanding photochromicity is essential for developing new means of modulating the optical properties and optical response of materials. Here, we report on the synthesis and exciting new photochromic behavior of Nb5+ doped TiO2 nanoparticle colloids (NCs). We find that in hole scavenging media, Nb5+ doping significantly improves the photochromic response time of TiO2 nanoparticles. In the infrared regime, Nb-doped TiO2 NCs exhibit an order of magnitude faster photoresponse kinetics than the pristine TiO2. Enhanced photochromic response is observed in the visible light regime as well. The transmittance of Nb-doped TiO2 NCs drops to 10% in less than 2 minutes when irradiated by UV light in…
Performance and characterization of the FinEstBeAMS beamline at the MAX IV Laboratory
European Regional Development Fund (grant No. TK-141 HiTechDevices 2014-2020.4.01.15-0011 to University of Tartu; grant No. MAX-TEENUS 2014-2020.4.01.20-0278 to University of Tartu; grant No. Eesti Kiirekanal SLOFY11156T/1 to University of Tartu); Estonian Research Council (grant No. PRG-629 to University of Tartu); Jane & Aatos Erkko Foundation (grant No. SOFUS); Business Finland (grant No. 1464/31/2019); Academy of Finland (grant No. 319042; grant No. 326461; grant No. 326406; grant No. 320165); University of Oulu; University of Turku; Tampere University; University of Tartu.
Reversible Photodoping of TiO2 Nanoparticles for Photochromic Applications
Financial support from the Estonian Research Council (IUT2-25, IUT2-26, and PUTJD680) is gratefully acknowledged. This work was supported by the Academy of Finland (decision numbers 141481 and 286713) and by the EU through the European Regional Development Fund (Center of Excellence for Zero Energy and Resource Efficient Smart Buildings and Districts-ZEBE, 2014-2020.4.01.15-0016). Work is supported by the Latvian Academy of Sciences in the framework of FLPP (Plasmonic oxide quantum dots for energy saving smart windows, lzp-2018/1-0187).
Improved antifouling properties and selective biofunctionalization of stainless steel by employing heterobifunctional silane-polyethylene glycol overlayers and avidin-biotin technology
AbstractA straightforward solution-based method to modify the biofunctionality of stainless steel (SS) using heterobifunctional silane-polyethylene glycol (silane-PEG) overlayers is reported. Reduced nonspecific biofouling of both proteins and bacteria onto SS and further selective biofunctionalization of the modified surface were achieved. According to photoelectron spectroscopy analyses, the silane-PEGs formed less than 10 Å thick overlayers with close to 90% surface coverage and reproducible chemical compositions. Consequently, the surfaces also became more hydrophilic, and the observed non-specific biofouling of proteins was reduced by approximately 70%. In addition, the attachment of E…