Characterization of a Modified Expansion Condensation Particle Counter for Detection of Nanometer-Sized Particles
A newly developed condensation particle counter provides measurements of aerosol particle number densities for size diameters as low as 3 nm. This Expansion Condensation Particle Counter (ECPC) operates based on fast adiabatic expansion with specialized detection and evaluation of the temporal development of light scattered by the ensemble of growing droplets. In its new configuration the ECPC has been modified such that a previously needed calibration factor became obsolete. In this article the new design is described which now includes a fast pressure sensor for monitoring the pressure drop inside the measurement chamber. Extensive laboratory experiments for characterizing the ECPC are de…
Enhanced organic mass fraction and decreased hygroscopicity of cloud condensation nuclei (CCN) during new particle formation events
In a forested near-urban location in central Germany, the CCN efficiency of particles smaller than 100 nm decreases significantly during periods of new particle formation. This results in an increase of average activation diameters, ranging from 5 to 8% at supersaturations of 0.33% and 0.74%, respectively. At the same time, the organic mass fraction in the sub-100-nm size range increases from approximately 2/3 to 3/4. This provides evidence that secondary organic aerosol (SOA) components are involved in the growth of new particles to larger sizes, and that the reduced CCN efficiency of small particles is caused by the low hygroscopicity of the condensing material. The observed dependence of…