0000000000611940

AUTHOR

Ryuta Miyatake

showing 2 related works from this author

Bis[S-hexyl 3-(thiophen-2-ylmethylidene)dithiocarbazato-κ2N3,S]palladium(II)

2016

In the title complex, [Pd(C12H17N2S3)2], the PdIIatom exhibits a square-planar coordination geometry with theN,S-chelating ligands arranged in atransconfiguration. Intramolecular C—H...S hydrogen bonds are observed. In the crystal, molecules are linked by weak C—H...N hydrogen-bond interactions, forming chains parallel to thebaxis.

inorganic chemicalsQuantitative Biology::Biomoleculescrystal structureChemistryStereochemistryHydrogen bondThio-chemistry.chemical_elementGeneral MedicineCrystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesMedicinal chemistryhumanitiespalladium(II) complex0104 chemical sciencesCrystalTrans configurationlcsh:QD901-999lcsh:Crystallographydithiocarbazate ligandCoordination geometryPalladiumIUCrData
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Crystal structure ofS-octyl (E)-3-(4-methoxybenzylidene)dithiocarbazate

2015

As already observed in similar molecules, the dithiocarbazate group in the title compound, C17H26N2OS2, adopts anEEconfiguration with respect to the C=N bond of the benzylidene moiety. In the crystal, molecules are connected into inversion dimers by pairs of N—H...S hydrogen bonds. The dimers are linked by weak π–π interactions, with centroid-to-centroid distances of 3.723 (11) Å, forming chains parallel to [110].

crystal structureCrystallographyChemistryHydrogen bonddithiocarbazateThio-General ChemistryCrystal structurehydrogen bondingCondensed Matter PhysicsData ReportsCrystalCrystallographyQD901-999S-containing Schiff basesdi­thio­carbazateMoietyGeneral Materials ScienceActa Crystallographica Section E Crystallographic Communications
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