6533b827fe1ef96bd1285e14

RESEARCH PRODUCT

Bis[S-hexyl 3-(thiophen-2-ylmethylidene)dithiocarbazato-κ2N3,S]palladium(II)

Ennio ZangrandoRyuta MiyatakeBegumMd. Chanmiya SheikhK. Begum

subject

inorganic chemicalsQuantitative Biology::Biomoleculescrystal structureChemistryStereochemistryHydrogen bondThio-chemistry.chemical_elementGeneral MedicineCrystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesMedicinal chemistryhumanitiespalladium(II) complex0104 chemical sciencesCrystalTrans configurationlcsh:QD901-999lcsh:Crystallographydithiocarbazate ligandCoordination geometryPalladium

description

In the title complex, [Pd(C12H17N2S3)2], the PdIIatom exhibits a square-planar coordination geometry with theN,S-chelating ligands arranged in atransconfiguration. Intramolecular C—H...S hydrogen bonds are observed. In the crystal, molecules are linked by weak C—H...N hydrogen-bond interactions, forming chains parallel to thebaxis.

https://doi.org/10.1107/s2414314616011329