0000000000619989
AUTHOR
V. Muñoz-san José
Characterization of non-polar ZnO layers with positron annihilation spectroscopy
We applied positron annihilation spectroscopy to study the effect of growth polarity on the vacancy defects in ZnO grown by metal-organic vapor phase deposition on sapphire. Both c-plane and a-plane ZnO layers were measured, and Zn vacancies were identified as the dominant defects detected by positrons. The results are qualitatively similar to those of earlier experiments in GaN. The Zn vacancy concentration decreases in c-plane ZnO by almost one order of magnitude (from high 10 cm−3 to low 10 cm−3) when the layer thickness is increased from 0.5 to 2 μm. Interestingly, in a-plane ZnO the Zn vacancy concentration is constant at a level of about 2×10 cm−3 in all the samples with thicknesses v…
Quantum dots of Cd0.5Mn0.5Te semimagnetic semiconductor formed by the cold isostatic pressure method
Abstract Cd0.5Mn0.5Te is a semimagnetic semiconductor, which crystallizes in the zinc-blende structure (ZB) and exhibits a magnetic spin glass like transition at 21 K. Under pressure it shows a first-order phase transition around 2.6 GPa to the NaCl like structure. In this work, the pressure cycled method using a Paris–Edinburgh cell up to 8 GPa has been applied to Cd0.5Mn0.5Te samples in order to obtain recovered nanocrystals. The nanoparticles have been characterized by EDX and electron microscopy. The X-ray and electron diffraction results confirmed the existence of nanocrystals in the ZB phase with an average size of 7 nm. Magnetization measurements made in the range of 2–300 K at low f…
II–VI and II1−xMnxVI semiconductor nanocrystals formed by the pressure cycle method
II–VI and II1−x Mn x VI nanocrystals were prepared by the pressure cycle method using the Paris–Edinburgh cell. The recovered samples are nanocrystals in the cubic phase zinc-blend (ZB) structure and were characterized using transmission electron microscopy, electron diffraction, X-ray diffraction and Raman scattering. Transmission electron micrographs show that these nanocrystals are nearly spherical with diameters ranging from 20 to 50 nm depending on the sample under investigation. The Raman scattering measurements confirm the existence of II–VI nanocrystals in the cubic phase (ZB). The magnetic properties of Cd0.5Mn0.5Te nanoparticles were found to vary with the particle size and were d…