A comparison of different methods for speleothem age modelling
Abstract Speleothems, such as stalagmites and flowstones, can be dated with unprecedented precision in the range of the last 650,000 a by the 230Th/U-method, which is considered as one of their major advantages as climate archives. However, a standard approach for the construction of speleothem age models and the estimation of the corresponding uncertainty has not been established yet. Here we apply five age modelling approaches ( StalAge , OxCal, a finite positive growth rate model and two spline-based models) to a synthetic speleothem growth model and two natural samples. All data sets contain problematic features such as outliers, age inversions, large and abrupt changes in growth rate a…
Lignin oxidation products in soil, dripwater and speleothems from four different sites in New Zealand
Lignin oxidation products (LOPs) are widely used as vegetation proxies in climate archives, such as sediment and peat cores. The total LOP concentration, Σ8, provides information on the abundance of vegetation, while the ratios C/V and S/V of the different LOP groups also provide information on the type of vegetation. Recently, LOP analysis has been successfully applied to speleothem archives. However, there are many open questions concerning the transport and microbial degradation of LOPs on their way from the soil into the cave system. These processes could potentially alter the original source-dependent LOP signals, in particular the C/V and S/V ratios, and thus complicate their interpre…