Author: N. V. Devika

0000000000639373

AUTHOR

N. V. Devika

showing 2 related works from this author

An exclusive approach to 3,4-disubstituted cyclopentenes and alkylidene cyclopentenes via the palladium catalyzed ring opening of azabicyclic olefins…

2013

A simple and efficient method for the stereoselective ring opening of bicyclic hydrazines with various aryl halides under palladium catalysis has been elaborated. The reactions afforded trans-3,4-disubstituted cyclopentenes or alkylidene cyclopentenes in good to excellent yields. By taking advantage of multiple points of functionalization in the synthesized trans-3-phenyl-4-hydrazino-cyclopentene, we have synthesized the antidepressant Cypenamine (trans-2-phenylcyclopentylamine).

Bicyclic moleculeChemistryGeneral Chemical EngineeringArylchemistry.chemical_elementHalideGeneral ChemistryRing (chemistry)Medicinal chemistryCatalysischemistry.chemical_compoundReagentOrganic chemistryStereoselectivityta116PalladiumRSC Advances

researchProduct

CCDC 782677: Experimental Crystal Structure Determination

2013

Related Article: Nayana Joseph,Rani Rajan,Jubi John,N. V. Devika,S. Sarath Chand,E. Suresh,Petri M. Pihko,K. V. Radhakrishnan|2013|RSC Advances|3|7751|doi:10.1039/c3ra41504j

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDi-isopropyl 1-(2-(2-aminophenyl)cyclopent-3-en-1-yl)hydrazine-12-dicarboxylateExperimental 3D Coordinates

researchProduct

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