0000000000640553
AUTHOR
Fulvio Coletti
Dating archaeological strata in the Magna Mater temple using solid-state voltammetric analysis of leaded bronze coins
[EN] The application of solid state electrochemistry techniques for dating archaeological strata using lead-containing bronze coins is described. The proposed methodology was applied to samples coming from the Roman archaeological site of Magna Mater Temple (Rome, Italy) occurring in different strata dating back between the second half and the end of the 4(th) century A.D. and the 20(th) century. The voltammetric signatures of copper and lead corrosion products in contact with aqueous acetate buffer, as well as the catalytic effects produced on the hydrogen evolution reaction, were used for establishing the age of different strata and dating coins belonging to unknown age. Voltammetric data…
Electrochemical discrimination of manufacturing types of pottery from Magna Mater Temple and Fora of Nerva and Caesar (Rome, Italy)
Abstract The voltammetry of immobilized microparticles (VIMP) methodology is applied to a series of pottery samples from the Roman sites of Nerva's Forum (second half of 9th-early 11th A.D), Caesar's Forum (second half of 9th-early 11th A.D) and Magna Mater Temple (III century). The VIMP sampling applied to voltammetric and electrochemical impedance spectroscopy (EIS) measurements was applied by the first time to acquire archaeometric information on archaeological pottery. VIMP measurements using pressed sample pellets on gold electrodes in contact with air-saturated 0.10 M H2SO4 have permitted to detect voltammetric signals for the reduction/oxidation of Fe and Mn minerals as well as catal…
Archaeometric analysis of Roman bronze coins from the Magna Mater temple using solid-state voltammetry and electrochemical impedance spectroscopy
Voltammetry of microparticles (VMP) and electrochemical impedance spectroscopy (EIS) techniques, complemented by SEM-EDX and Raman spectroscopy, were applied to a set of 15 Roman bronze coins and one Tessera from the temple of Magna Mater (Rome, Italy). The archaeological site, dated back between the second half and the end of the 4th century A.D., presented a complicated stratigraphic context. Characteristic voltammetric patterns for cuprite and tenorite for sub-microsamples of the corrosion layers of the coins deposited onto graphite electrodes in contact with 0.10 M HClO4 aqueous solution yielded a grouping of the coins into three main groups. This grouping was confirmed and refined usin…