Author: Novi Wijaya

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AUTHOR

Novi Wijaya

showing 3 related works from this author

ChemInform Abstract: Thioetherification of Chloroheteroarenes: A Binuclear Catalyst Promotes Wide Scope and High Functional-Group Tolerance.

2015

The nucleophilic substitution of a variety of chloro- and bromohetarenes with arylthiols is optimized to use [PdCl(allyl)]2 in combination with a ferrocenyltetraphosphane as ligand.

chemistry.chemical_compoundScope (project management)LigandChemistryFunctional groupNucleophilic substitutionGeneral MedicineCombinatorial chemistryCatalysisChemInform

researchProduct

Thioetherification of Chloroheteroarenes: A Binuclear Catalyst Promotes Wide Scope and High Functional-Group Tolerance

2014

A constrained binuclear palladium catalyst system affords selective thioetherification of a wide range of functionalized arenethiols with chloroheteroaromatic partners with the highest turnover numbers (TONs) reported to date and tolerates a large variety of reactive functions. The scope of this system includes the coupling of thiophenols with six- and five-membered 2-chloroheteroarenes (i.e., functionalized pyridine, pyrazine, quinoline, pyrimidine, furane, and thiazole) and 3-bromoheteroarenes (i.e., pyridine and furane). Electron-rich congested thiophenols and fluorinated thiophenols are also suitable partners. The coupling of unprotected amino-2-chloropyridines with thiophenol and the s…

Models MolecularHalogenationPyrazinePhosphinesPyridineschemistry.chemical_elementSulfidesLigandsCatalysisCatalysischemistry.chemical_compoundPhenolsPyridineOrganic chemistrySulfhydryl CompoundsFuransThiazoleThiophenolOrganic ChemistryQuinolineGeneral ChemistryCombinatorial chemistryThiazoleschemistryPyrazinesFunctional groupQuinolinesPalladiumPalladiumChemistry - A European Journal

researchProduct

CCDC 902497: Experimental Crystal Structure Determination

2014

Related Article: Mélanie Platon, Novi Wijaya, Vincent Rampazzi, Luchao Cui, Yoann Rousselin, Mark Saeys, Jean-Cyrille Hierso|2014|Chem.-Eur.J.|20|12584|doi:10.1002/chem.201403337

Space GroupCrystallographyCrystal System(mu~2~-11'33'-tetrakis(Diphenylphosphino)ferrocene)-dichloro-bis(dichloromethyl)-di-palladium chloroform solvateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

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