The fate of subducted oceanic slabs in the shallow mantle: Insights from boron isotopes and light element composition of metasomatized blueschists from the Mariana forearc.
Abstract Serpentine muds from South Chamorro Seamount (SCS), drilled during ODP Leg 195 at Site 1200 contain metamafic clasts that experienced blueschist-facies metamorphism (including the critical mineral assemblage pumpellyite – Na-amphibole – epidote). These schists represent fragments from the actual slab–mantle interface at ~ 27 km depth. Their heterogeneous lithology with a metasomatic character indicates significant mobility of major elements in the Mariana forearc, a region of melange formation as it can also be observed in onland exposures such as the Catalina Schist. As the Mariana forearc blueschists show no late stage alteration they permit the direct study of material transfer …
Evidence for boron incorporation into the serpentine crystal structure
Serpentinite mud volcanoes from the Mariana forearc comprise B-rich mantle wedge peridotites serpentinized by slab fluids. The major component of these rocks are serpentine group minerals [Mg 3 Si 2 O 5 (OH) 4 ], showing highly variable textural and geochemical features. Micro-Raman spectroscopy reveals that the serpentine minerals are well-crystallized lizardite and chrysotile. In situ SIMS spot analyses and element mapping via ToF-SIMS show that B is evenly distributed across serpentine grains, suggesting that serpentine, both lizardite and chrysotile in different textural regions, can host significant amounts of B (up to ~200 μg/g) into its crystal structure. As such structurally bound B…