Carboniferous high-potassium I-type granitoid magmatism in the Eastern Pontides: The Gümüşhane pluton (NE Turkey)
The Gumushane pluton, a high-K calc-alkaline I-type granodionte/granite complex, forms an important component of the pre-Liassic basement of the Eastern Pontides (NE Turkey) In its eastern part, the pluton shows a compositional zonation ranging from biotite-hornblende granodiorite in the NW through biotite-hornblende granite to leucogranite/granophyre in the SE Numerous mafic microgranular enclaves (up to similar to 40 cm in diameter) suggest the former presence of globules of mafic melt during crystallization Emplacement of the pluton occurred during the latest Early Carboniferous, as shown by the 320 +/- 4 Ma Ar-40-Ar-39 bionte/homblende and 324 +/- 6 Ma LA-ICP-MS U-Pb zircon ages. In Har…
Investigation of Li/Ca variations in aragonitic shells of the ocean quahogArctica islandica, northeast Iceland
Interannual and intra-annual variations in lithium-to-calcium ratio were investigated with high temporal resolution in the aragonitic outer shell layer of juvenile Arctica islandica (Mollusca; Bivalvia) collected alive in 2006 off northeast Iceland. Li/Ca shell ranged between 7.00 and 11.12 µmol mol -1 and presented well-marked seasonal cycles with minimum values recorded at the annual growth lines; a general pattern was a progressive increase in Li/Ca shell from March to May, followed by a plateau in June and a decrease down to minimum values in July-August. Li/Ca shell was correlated with d 18 O shell -derived temperature, but the strength of this relationship was weak ( r 2 p shell in A.…
Negative Ce anomalies in Mn oxides: The role of Ce4+ mobility during water–mineral interaction
We present one of the very rare natural examples of extremely negative Ce anomalies (up to 4 orders of magnitude) in manganese oxides, caused by higher mobility of Ce4+ compared to REE3+ in an aquatic environment. The young secondary Mn oxides formed together with fluorites and goethites during water–mineral interaction in a hydrothermal fluorite vein. Our findings are in contrast to the oxidative scavenging of Ce, which is commonly observed in Mn oxides. Comparison of REE patterns from modern mine waters with primary and secondary minerals demonstrates that this cannot be solely explained as a source-related feature or by immobilization of Ce, but must at least partially be the result of p…
Sinistral transport along the Trans-European Suture Zone: detrital zircon–rutile geochronology and sandstone petrography from the Carboniferous flysch of the Pontides
AbstractThe Lower Carboniferous flysch of the Istanbul Zone in Turkey is an over 1500 m thick turbiditic sandstone–shale sequence marking the onset of the Variscan deformation in the Pontides. It overlies Lower Carboniferous black cherts and is unconformably overlain by Lower Triassic continental sandstones and conglomerates. The petrography of the Carboniferous sandstones and the geochronology and geochemistry of the detrital zircons and rutiles were studied to establish the provenance of the clastic rocks. The sandstones are feldspathic to lithic greywackes and subgreywackes with approximately equal amounts of quartz, feldspar and lithic clasts. The amount of quartz and lithic fragments d…
Jurassic Ophiolite Formation And Emplacement As Backstop To A Subduction-Accretion Complex In Northeast Turkey, The Refahiye Ophiolite, And Relation To The Balkan Ophiolites
International audience; The eastern Mediterranean region within the Tethyan realm shows a high concentration of ophiolites with contrasting times of formation and emplacement along the belt: In the Balkans, the ophiolites formed during the early to medial Jurassic, and were obducted during the late Jurassic, whereas in Turkey and farther east, structurally intact Jurassic ophiolites are rare and Jurassic ophiolite obduction is unknown. Here we report a structurally intact, large ophiolite body of early Jurassic age from NE Turkey, the Refahiye ophiolite, located close to the suture zone between the Eastern Pontides and the Menderes-Taurus block. The Refahiye ophiolite forms an outcrop belt,…
The Othris Ophiolite, Greece: A snapshot of subduction initiation at a mid-ocean ridge
The mantle section of the Tethyan-type Othris Ophiolite, Greece, records tectono-magmatic processes characteristic of both mid-ocean ridges and supra-subduction zones. The Othris Ophiolite is a remnant of the Jurassic Neotethys Ocean, which existed between Eurasia and Gondwanaland. Othris peridotites range from fertile plagioclase lherzolites to depleted harzburgites. Abundances of Al2O3 and CaO show well-defined inverse linear correlations with MgO, suggesting that the Othris peridotites formed as residua from variable degrees of partial melting. Peridotites from the Fournos Kaitsa and western Katachloron sub-massifs are similar to abyssal peridotites and can be explained by a multistage m…