0000000000651622

AUTHOR

H. Johnson Jeyakumar

showing 2 related works from this author

2-(Benzylsulfanyl)pyridineN-oxide

2008

In the title compound, C12H11NOS, the dihedral angle between the oxopyridinium and phenyl rings is 58.40 (1)°. The crystal structure is stabilized by C—H...O hydrogen bonds, π–π stacking interactions involving the pyridinium rings [centroid–centroid distance = 3.6891 (9) Å] and C—H...π interactions.

CrystallographyHydrogen bondStackingPyridine-N-oxideGeneral ChemistryCrystal structureDihedral angleCondensed Matter Physicscomputer.software_genreOrganic Paperschemistry.chemical_compoundCrystallographychemistryQD901-999General Materials SciencePyridiniumData miningcomputerActa Crystallographica Section E Structure Reports Online
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2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate

2008

In the title compound, C15H17NOS·H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intramolecular S...O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal structure is stabilized by intermolecular O—H...O and weak C—H...O hydrogen bonds. In addition, weak π–π stacking interactions with a centroid–centroid distance of 3.778 (3) Å are also observed.

ChemistryHydrogen bondStackingPyridine-N-oxideGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsBioinformaticsOrganic Paperslcsh:Chemistrychemistry.chemical_compoundCrystallographylcsh:QD1-999PyridineGeneral Materials ScienceBenzeneActa Crystallographica Section E
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