6533b85efe1ef96bd12bfe0c
RESEARCH PRODUCT
2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate
B. Ravindran Durai NayagamH. Johnson JeyakumarDieter SchollmeyerSamuel Robinson Jebassubject
ChemistryHydrogen bondStackingPyridine-N-oxideGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsBioinformaticsOrganic Paperslcsh:Chemistrychemistry.chemical_compoundCrystallographylcsh:QD1-999PyridineGeneral Materials ScienceBenzenedescription
In the title compound, C15H17NOS·H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intramolecular S...O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal structure is stabilized by intermolecular O—H...O and weak C—H...O hydrogen bonds. In addition, weak π–π stacking interactions with a centroid–centroid distance of 3.778 (3) Å are also observed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-09-01 | Acta Crystallographica Section E |