An on-line system for preconcentration and determination of lead in wine samples by FAAS

2002

A flow injection method has been developed for the direct determination of free available Pb(II) and total Pb content in wine samples. The method is based on the chemical sorption of Pb(II), from pH 7 buffered solutions, on a packed polyurethane foam column, modified by addition of 2-(2-benzothiazolylazo)-p-cresol (BTAC). After this step, lead was directly eluted with a stream of 0.1 mol l(-1) HCl into an air C(2)H(2) flame in which lead was determined by atomic absorption spectrometry. Total lead was analyzed after sample digestion with nitric acid and hydrogen peroxide, being free available lead determined by direct sample on-line preconcentration and elution. The method provides a limit …