0000000000658420
AUTHOR
Frank Keppler
showing 10 related works from this author
Warm season precipitation signal in δ 2 H values of wood lignin methoxyl groups from high elevation larch trees in Switzerland
2017
RATIONALE In this study, we tested stable hydrogen isotope ratios of wood lignin methoxyl groups (δ 2Hmethoxyl values) as a palaeoclimate proxy in dendrochronology. This is a quite new method in the field of dendrochronology and the sample preparation is much simpler than the methods used before to measure δ2H values from wood. METHODS We measured δ 2Hmethoxyl values in high elevation larch trees (Larix decidua Mill.) from Simplon Valley (southern Switzerland). Thirty-seven larch trees were sampled and five individuals analysed for their δ 2Hmethoxyl values at annual (1971-2009) and pentadal resolution (1746-2009). The δ 2Hmethoxyl values were measured as CH3I released upon treatment of the…
Annually resolved δ<sup>2</sup>H tree-ring chronology of the lignin methoxyl groups from Germany reflects averaged Wester…
2019
Abstract. Stable hydrogen isotopes ratios of lignin methoxyl groups (expressed as δ2HLM) of wood have been shown to reflect the climate-sensitive δ2H values of precipitation (expressed as δ2Hprecip) modulated by a large uniform negative isotope fractionation. However, a detailed calibration study among temporal variabilities of δ2HLM in tree-ring series, site-specific δ2Hprecip and climate parameters has not been performed yet. Here, we present annually resolved δ2HLM values from nine tree-ring series (derived from four Fagus sylvatica L. trees) collected near stations of the Global Isotope Network of Isotopes in Precipitation (GNIP) and the Deutsche Wetterdienst (DWD) meteorological observ…
D/H ratios of methoxyl groups of the sedimentary organic matter of Lake Holzmaar (Eifel, Germany): A potential palaeoclimate/-hydrology proxy
2014
Stable hydrogen isotope ratios (dD values) of methoxyl groups in lignin and pectin from a variety of plant types from different locations have been shown to mirror dD values of precipitation, with a mean uniform isotopic fractionation. Since dD in precipitation is mainly influenced by climatic conditions, including temperature, evaporation and precipitation amount, methoxyl groups of organic matter have been proposed as a potential palaeoclimate proxy. Here, we measured the dD values of the methoxyl groups of sedimentary organic matter derived from sediment core segments of Lake Holzmaar (Eifel, Germany). The sediment core covers the entire Holocene and part of the Late Glacial (until 13,65…
Methane oxidation in industrial biogas plants-Insights in a novel methanotrophic environment evidenced by pmoA gene analyses and stable isotope label…
2018
Abstract A broad methanotrophic community consisting of 16 different operational taxonomic units (OTUs) was detected by particulate methane monooxygenase A (pmoA) gene analyses of reactor sludge samples obtained from an industrial biogas plant. Using a cloning-sequencing approach, 75% of the OTUs were affiliated to the group of type I methanotrophs (γ-Proteobacteria) and 25% to type II methanotrophs (α-Proteobacteria) with a distinct predominance of the genus Methylobacter. By database matching, half of the total OTUs may constitute entirely novel species. For evaluation of process conditions that support growth of methanotrophic bacteria, qPCR analyses of pmoA gene copy numbers were perfor…
Climate signals in δ13C of wood lignin methoxyl groups from high-elevation larch trees
2016
Abstract In this study, a barely used method to measure δ13C values from lignin methoxyl groups (δ13Cmethoxyl) of tree‐rings is applied to high alpine larch trees to test their potential as a climate proxy. Thirty-seven larch trees (Larix decidua Mill.) were sampled at a tree line site near Simplon Village in the Valais/Switzerland. Samples were used to measure tree-ring width, and from five individuals, δ13Cmethoxyl was determined at annual resolution from 1971 to 2009, and at pentadal resolution from 1747 to 2009. The physiological tree responses to increasing atmospheric CO2 concentration since 1850 and the corresponding decrease in δ13C (Suess effect) were corrected using a range of pub…
Tree-ring δ2H values from lignin methoxyl groups indicate sensitivity to European-scale temperature changes
2020
Abstract Stable hydrogen isotope ratios of lignin methoxyl groups (δ2HLM) of wood have been shown to reflect climate-sensitive δ2H values of precipitation (δ2Hprecip). However, a detailed calibration study between high-resolution δ2HLM and δ2Hprecip data has not been performed yet. Here, we present annually resolved δ2HLM values from nine tree-ring series (derived from four Fagus sylvatica L. trees) collected near a station of the Global Isotope Network of Isotopes in Precipitation (GNIP) and the meteorological observatory at Hohenpeisenberg (Germany; ~48°N, 11°E). The nine δ2HLM tree-ring series show highly significant inter-series correlations (Rbar = 0.52) over the common period of overl…
Nitrous oxide effluxes from plants as a potentially important source to the atmosphere
2018
The global budget for nitrous oxide (N2 O), an important greenhouse gas and probably dominant ozone-depleting substance emitted in the 21st century, is far from being fully understood. Cycling of N2 O in terrestrial ecosystems has traditionally exclusively focused on gas exchange between the soil surface (nitrification-denitrification processes) and the atmosphere. Terrestrial vegetation has not been considered in the global budget so far, even though plants are known to release N2 O. Here, we report the N2 O emission rates of 32 plant species from 22 different families measured under controlled laboratory conditions. Furthermore, the first isotopocule values (δ15 N, δ18 O and δ15 Nsp ) of …
Climate signals in stable carbon and hydrogen isotopes of lignin methoxy groups from southern German beech trees
2021
Stable hydrogen and carbon isotope ratios of wood lignin methoxy groups (δ13CLM and δ2HLM values) have been shown to be reliable proxies of past temperature variations. Previous studies showed that δ2HLM values even work in temperate environments where classical tree-ring width and maximum latewood density measurements are less successful for climate reconstructions. Here, we analyse the annually resolved δ13CLM values from 1916–2015 of four beech trees (Fagus sylvatica) from a temperate site near Hohenpeißenberg in southern Germany and compare these data with regional- to continental-scale climate observations. Initial δ13CLM values were corrected for the Suess effect (a decrease of δ13C i…
δ2H, δ13C and δ18O from whole wood,α-cellulose and lignin methoxyl groups inPinus sylvestris: a multi-parameter approach
2015
Novel tree ring parameters – δ13C and δ2H from methoxyl groups – have been developed to reconstruct palaeoclimate. Tests with δ13C and δ18O derived from whole wood and cellulose samples, however, indicated differences in the isotopic composition and climate signal, depending on the extracted wood component. We assess this signal dependency by analysing (i) δ13C and δ18O from whole wood and cellulose and (ii) δ13C and δ2H from methoxyl groups, using Pinus sylvestris L. growing near Altenkirchen (Germany). Results indicate significant correlations among the time series derived from whole wood, cellulose, and lignin methoxyl groups. Compared with the whole wood samples, δ13C from methoxyl grou…
Annually resolved δ2H tree-ring chronology of the lignin methoxyl groups from Germany reflects averaged Western European surface air temperatur…
2019
Stable hydrogen isotopes ratios of lignin methoxyl groups (expressed as δ2HLM) of wood have been shown to reflect the climate-sensitive δ2H values of precipitation (expressed as δ2Hprecip) modulated by a large uniform negative isotope fractionation. However, a detailed calibration study among temporal variabilities of δ2HLM in tree-ring series, site-specific δ2Hprecip and climate parameters has not been performed yet. Here, we present annually resolved δ2HLM values from nine tree-ring series (derived from four Fagus sylvatica L. trees) collected near stations of the Global Isotope Network of Isotopes in Precipitation (GNIP) and the Deutsche Wetterdienst (…