0000000000668365

AUTHOR

Sarmite Katkevica

showing 2 related works from this author

Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F–BEACh 2014 field study

2017

Abstract. The chemical composition of organic aerosols was analyzed using complementary mass spectrometric techniques during a field study in Central Europe in July 2014 (Fichtelgebirge – Biogenic Emission and Aerosol Chemistry, F–BEACh 2014). Aerosols were analyzed in real-time by Aerosol Flowing Atmospheric-Pressure Afterglow Mass Spectrometry (AeroFAPA–MS), Aerosol Mass Spectrometry (AMS), and Chemical Ionization Atmospheric-Pressure interface Time-of-Flight Mass Spectrometry (CI–APiToF–MS). In addition, offline detection of acidic organic compounds was conducted by non-target screening of filter samples using High Resolution Mass Spectrometry (HRMS) in combination with Ultra-High Pressu…

Atmospheric Science010504 meteorology & atmospheric sciencesAnalytical chemistrychemistry.chemical_element010501 environmental sciencesMass spectrometry010402 general chemistry01 natural scienceslcsh:Chemistrychemistry.chemical_compoundRelative humiditySulfateChemical composition0105 earth and related environmental sciences010401 analytical chemistry[CHIM.CATA]Chemical Sciences/CatalysisParticulatesSulfur[SDE.ES]Environmental Sciences/Environmental and Societylcsh:QC1-999Aerosol0104 chemical scienceslcsh:QD1-999chemistry13. Climate actionEnvironmental chemistryHYSPLITlcsh:Physics
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Lewis acid-catalyzed Beckmann rearrangement of ketoximes in ionic liquids

2009

Abstract The Beckmann rearrangement of five ketoximes was done in 17 different ionic liquids by using four Lewis acids. The effect of the type of cation and the type of anion in the ionic liquid on the rate of the rearrangement reaction and product composition is compared and discussed. The effects of the hydrophobicity and the hydrogen bonding ability of ionic liquids on the rearrangement of ketoximes were investigated, as well as the catalytical activity of the Lewis acids.

Hydrogen bondProcess Chemistry and TechnologyGeneral ChemistrySigmatropic reactionCatalysisIonCatalysischemistry.chemical_compoundchemistryBeckmann rearrangementIonic liquidPolymer chemistryOrganic chemistryRearrangement reactionLewis acids and basesCatalysis Communications
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