0000000000671626
AUTHOR
I. B. Bolotova
High resolution analysis of the SO2 spectrum in the 2600–2900cm−1 region: 2ν3, ν2+2ν3−ν2 and 2ν1+ν2 bands
Abstract Infrared spectrum of the SO 2 molecule was recorded with high resolution in the 2600– 2900 cm − 1 region. Spectrum was recorded with the Fourier transform interferometer Bruker IFS-120 HR in Oulu (Finland) with the pressure of 111 Pa and the absorption path length of 163.2 m that allowed us to record 2 ν 3 and 2 ν 1 + ν 2 weak bands. The 2 ν 3 band discussed earlier by Lafferty et al., was re-analyzed, and considerably more information was extracted from the spectrum (more than 3800 transitions of the 2 ν 3 band were assigned in the experimental spectrum with maximum values of quantum numbers, J max . = 76 and K a max . = 26 ). On the basis of the procedure discussed in Ulenikov et…
High Resolution Study of the v1 + 2v2 −v2 and 2v2 + v3 − v2 ”Hot” Bands and Ro-Vibrational Re-Analysis of the v1 + v2/v2 + v3/3v3 Poliad of the SO2 Molecule
The main goal of the present study was to analyse rotational stuctures of two excited vibrational states, (120) and (021). Because both the band, v1+2v2 and 2v2+v3 one are extremally weak, a special efforts were faired to record very weak hot bands, v1+2v2−v2 and 2v2+v3−v2.Both of those bands are located in the region of considerably more stronger combinational bands, v1 + v2 and v2 + v3. On that reason, as the first step of analysis, we made assignments of transitions belonging to these v1 + v2 and v2 + v3 bands. As the result of analysis, we were able to assign three times more transitions to the bands v1 + v2 and v2 + v3 than it was known in the before literature. After "cleaning" the ex…