0000000000674590

AUTHOR

Milla Mattila

showing 6 related works from this author

Thiourea Based Tritopic Halogen Bonding Acceptors

2023

Series of thiourea based tritopic receptor molecules were synthesized to be used as building blocks for halogen-bonded assemblies. Here 16 new receptor molecules were synthesized from two different 2,4,6-trialkyl-1,3,5-tris(bromomethyl)benzene starting materials via tris(isothiocyanatomethyl)benzene intermediates. The alkyl substituents in the benzene ring showed to be important for isothiocyanate group formation instead of competing thiocyanate group. The synthesis route allowed us to synthesize the isothiocyanate intermediates and further the receptor molecules without typically used and highly toxic thiophosgene. Synthesized receptor molecules were used to study their halogen bond accept…

isothiocyanates and thiocyanatesnoncovalent interactionshalogeenithalogen bondingx-raydiffractionthiourea-based receptors
researchProduct

Chiral carbonyl hypoiodites

2023

Three chiral carbonyl hypoiodites, R–C(O)OI, have been prepared from N-protected (S)-valine to give the ligand-stabilised (S)-valinoyl hypoiodite complexes with 4-dimethylaminopyridine, 4-pyrrolidinopyridine, and 4-morpholinopyridine as the stabilising ligands. The identity of the complexes was established by NMR (1H, 13C, 1H–15N HMBC) and single crystal X-ray diffraction analysis. peerReviewed

Materials ChemistryMetals and AlloysCeramics and CompositesGeneral ChemistryCatalysiskarbonyylitSurfaces Coatings and FilmsElectronic Optical and Magnetic Materials
researchProduct

CCDC 2225069: Experimental Crystal Structure Determination

2023

Related Article: Milla Mattila, Kari Rissanen, Jas S. Ward|2023|Chem.Commun.|59|4648|doi:10.1039/D3CC00259D

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-(dimethylamino)pyridinium (S)-N-phthaloylvalinoyl hypoioditeExperimental 3D Coordinates
researchProduct

CCDC 2245212: Experimental Crystal Structure Determination

2023

Related Article: Milla Mattila, Kari Rissanen, Jas S. Ward|2023|Chem.Commun.|59|4648|doi:10.1039/D3CC00259D

Space GroupCrystallographyCrystal SystemCrystal Structure4-(pyridin-4-yl)morpholineCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2225071: Experimental Crystal Structure Determination

2023

Related Article: Milla Mattila, Kari Rissanen, Jas S. Ward|2023|Chem.Commun.|59|4648|doi:10.1039/D3CC00259D

Space GroupCrystallographyCrystal SystemCrystal Structure1-({[2-(13-dioxo-13-dihydro-2H-isoindol-2-yl)-3-methylbutanoyl]oxy}iodaniumyl)-4-(morpholin-4-yl)pyridineCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2225070: Experimental Crystal Structure Determination

2023

Related Article: Milla Mattila, Kari Rissanen, Jas S. Ward|2023|Chem.Commun.|59|4648|doi:10.1039/D3CC00259D

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct