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RESEARCH PRODUCT

Chiral carbonyl hypoiodites

Milla MattilaKari RissanenJas S. Ward

subject

Materials ChemistryMetals and AlloysCeramics and CompositesGeneral ChemistryCatalysiskarbonyylitSurfaces Coatings and FilmsElectronic Optical and Magnetic Materials

description

Three chiral carbonyl hypoiodites, R–C(O)OI, have been prepared from N-protected (S)-valine to give the ligand-stabilised (S)-valinoyl hypoiodite complexes with 4-dimethylaminopyridine, 4-pyrrolidinopyridine, and 4-morpholinopyridine as the stabilising ligands. The identity of the complexes was established by NMR (1H, 13C, 1H–15N HMBC) and single crystal X-ray diffraction analysis. peerReviewed

http://urn.fi/URN:NBN:fi:jyu-202304032363