0000000000679108
AUTHOR
Alfonso Salinas-castillo
In vitro evaluation of leishmanicidal properties of a new family of monodimensional coordination polymers based on diclofenac ligand
Some series of isostructural chains with general formula [M(diclof)(HO)]·(EtOH) have been obtained from reaction between diclofenac ligand (diclof) and first row transition salts (M = Mn (1),Ni (2) and Co (3)). These monodimensional coordination polymers have been characterized and their crystal structures have been solved by X-ray diffraction methods, elucidating isostructural compounds that are chains with water molecules acting as bridge between different metallic centers, while diclofenac ligands are coordinated to the octahedral coordination environment of the same. Magnetic studies of these complexes have revealed the existence of moderate ferromagnetic interactions among manganese, n…
Novel metal–organic frameworks based on 5-bromonicotinic acid: Multifunctional materials with H2 purification capabilities
Two new metal–organic frameworks based on 5-bromonicotinic acid complexes [Cd(5-BrNic)2]n (1) and [Co(5-BrNic)2(H2O)]n (2) have been synthesized by hydrothermal reactions of this ligand with cadmium and cobalt metallic(II) salts in the presence of water. Compound 1 displays intense photoluminescence properties in the solid state at room temperature, while 2 exhibits an antiferromagnetic interaction between Co(II) ions with a J value of −4.1 cm−1. Experimental studies, backed up by Monte Carlo simulations about adsorption, pore size distribution and accessible surface area reveal the capability of 2 for H2 purification applications.
CCDC 1884201: Experimental Crystal Structure Determination
Related Article: Amalia García-García, José M. Méndez-Arriaga, Rubén Martín-Escolano, Javier Cepeda, Santiago Gómez-Ruiz, Alfonso Salinas-Castillo, José M. Seco, Manuel Sánchez-Moreno, Duane Choquesillo-Lazarte, Ana B. Ruiz-Muelle, Ignacio Fernández, Clotilde Marín, Antonio Rodríguez-Diéguez|2020|Polyhedron|184|114570|doi:10.1016/j.poly.2020.114570
CCDC 1884200: Experimental Crystal Structure Determination
Related Article: Amalia García-García, José M. Méndez-Arriaga, Rubén Martín-Escolano, Javier Cepeda, Santiago Gómez-Ruiz, Alfonso Salinas-Castillo, José M. Seco, Manuel Sánchez-Moreno, Duane Choquesillo-Lazarte, Ana B. Ruiz-Muelle, Ignacio Fernández, Clotilde Marín, Antonio Rodríguez-Diéguez|2020|Polyhedron|184|114570|doi:10.1016/j.poly.2020.114570