0000000000680679

AUTHOR

Luis A. Oro

showing 2 related works from this author

Five coordinate complexes of the type Rh(SnCl3)(NBD)L2

1983

Several new rhodium complexes of general formulation Rh(SnCl3)(NBD)L2 (L=P(OMe)3, P(OMe)2Ph, P(OMe)Ph2, P(OEt)3, P(OEt)2Ph, P(OEt)Ph2, P(O-i-Pr)3, P(OPh)3) have been prepared and characterized by elemental analysis and by i.r. and n.m.r. spectroscopy. The complexes show low or no conductivity in acetone solution and react with carbon monoxide (1 atm).

Inorganic Chemistrychemistry.chemical_compoundchemistryStereochemistryMaterials ChemistryMetals and AlloysAcetonechemistry.chemical_elementOrganometallic chemistryCatalysisRhodiumCarbon monoxideTransition Metal Chemistry
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Preparation and Oxidative Addition Reactions of 8-Oxyquinolate Rhodium(I) Complexes

1986

Abstract The preparation of new 8-oxyquinolate rhodium(I) complexes of the general formula Rh(Oq) (L) (L') is described. They undergo oxidative addition reactions with halogens and methyl iodide to give the corresponding rhodium(III) complexes. NMR measurements are used in the characterization of the compounds.

Inorganic Chemistrychemistry.chemical_compoundchemistryHalogenPolymer chemistryOrganic chemistrychemistry.chemical_elementPhysical and Theoretical ChemistryOxidative additionMethyl iodideRhodiumSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
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