6533b82bfe1ef96bd128df0f

RESEARCH PRODUCT

Five coordinate complexes of the type Rh(SnCl3)(NBD)L2

Pascual LahuertaDaniel CarmonaJosefa ReyesLuis A. OroRafael Usón

subject

Inorganic Chemistrychemistry.chemical_compoundchemistryStereochemistryMaterials ChemistryMetals and AlloysAcetonechemistry.chemical_elementOrganometallic chemistryCatalysisRhodiumCarbon monoxide

description

Several new rhodium complexes of general formulation Rh(SnCl3)(NBD)L2 (L=P(OMe)3, P(OMe)2Ph, P(OMe)Ph2, P(OEt)3, P(OEt)2Ph, P(OEt)Ph2, P(O-i-Pr)3, P(OPh)3) have been prepared and characterized by elemental analysis and by i.r. and n.m.r. spectroscopy. The complexes show low or no conductivity in acetone solution and react with carbon monoxide (1 atm).

yearjournalcountryeditionlanguage
1983-02-01Transition Metal Chemistry
https://doi.org/10.1007/bf00618797