0000000000685369

AUTHOR

Rosa Corberán

showing 2 related works from this author

Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters.

2005

Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols. Sanau Torrecilla, Mercedes, Mercedes.Sanau@uv.es

UnprecedentedCatalytic diboration ; N-heterocyclic carbene ; Unprecedented ; SilverSilverUNESCO::QUÍMICA:QUÍMICA::Química orgánica [UNESCO]Metals and AlloysCatalytic diborationGeneral ChemistryGeneral Medicine:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysischemistry.chemical_compoundchemistryPolymer chemistryMaterials ChemistryCeramics and CompositesOrganic chemistryUNESCO::QUÍMICA::Química orgánicaN-heterocyclic carbeneCarbeneChemical communications (Cambridge, England)
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Highly stable Cp*-Ir(III) complexes with N-heterocyclic carbene ligands as C-H activation catalysts for the deuteration of organic molecules.

2006

The preparation of a series of complexes of the type CpIrX2(NHC) provides effective catalysts for the H/D exchange of a wide range of organic molecules in methanol-d4. The reaction proceeds with higher yields under milder reaction conditions than previous CpIr systems reported thus far. For comparative purposes, we also studied the catalytic activity of CpIrCl2(PMe3) under the same reaction conditions. The molecular structures of two of the new CpIr(NHC) complexes are described.

Reaction conditionschemistry.chemical_compoundColloid and Surface ChemistryChemistryStereochemistryGeneral ChemistryBiochemistryMedicinal chemistryCarbeneCatalysisCatalysisOrganic moleculesJournal of the American Chemical Society
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