6533b82cfe1ef96bd128eb10

RESEARCH PRODUCT

Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters.

Elena FernándezJesus RamirezRosa CorberánEduardo PerisMercedes Sanau

subject

UnprecedentedCatalytic diboration ; N-heterocyclic carbene ; Unprecedented ; SilverSilverUNESCO::QUÍMICA:QUÍMICA::Química orgánica [UNESCO]Metals and AlloysCatalytic diborationGeneral ChemistryGeneral Medicine:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysischemistry.chemical_compoundchemistryPolymer chemistryMaterials ChemistryCeramics and CompositesOrganic chemistryUNESCO::QUÍMICA::Química orgánicaN-heterocyclic carbeneCarbene

description

Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols. Sanau Torrecilla, Mercedes, Mercedes.Sanau@uv.es

yearjournalcountryeditionlanguage
2005-01-01Chemical communications (Cambridge, England)
10.1039/b503239chttps://pubmed.ncbi.nlm.nih.gov/15959583