0000000000686483

AUTHOR

Antonio A. García-valdivia

0000-0002-2399-1033

showing 8 related works from this author

Design of cost-efficient and photocatalytically active Zn-based MOFs decorated with Cu 2 O nanoparticles for CO 2 methanation

2019

<div>Here we show for the first time a MOF that is photocatalytically</div><div>active for the light-assisted CO<sub>2</sub> methanation at mild conditions</div><div>(215 °C) without the inclusion of metallic nanoparticles or any</div><div>sacrificial agent. The presence of Cu<sub>2</sub>O nanoparticles causes a 50 % increase in the photocatalytic activity. These results pave the way to developping efficient and cost-effective materials for CO<sub>2</sub> elimination.</div>

Materials science010405 organic chemistryMetals and AlloysNanoparticleGeneral ChemistryQuímica010402 general chemistry01 natural sciencesCatalysisSabatier reaction0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsChemical engineeringMethanationMaterials ChemistryCeramics and CompositesPhotocatalysisMetal-organic frameworkMetal nanoparticlesMaterialsChemical Communications
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Interpenetrated Luminescent Metal-Organic Frameworks based on 1H-Indazole-5-carboxylic Acid

2020

Herein we report the formation and characterization of two novel Zn-based multifunctional metal-organic frameworks (MOFs) based on 1H-indazole-5-carboxylic acid and bipyridine-like linkers, synthesized by soft solvothermal routes. These materials possess isoreticular 2-fold interpenetrated three-dimensional structures that afford a flexible character and allow porosity modulation of the MOFs as confirmed by CO2 sorption measurements. Apart from this attractive structural feature, the MOFs exhibit fascinating luminescent properties involving both luminescence thermometry and long-lasting phosphorescence.

chemistry.chemical_classificationIndazole010405 organic chemistryCarboxylic acidGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesCombinatorial chemistry0104 chemical sciences3. Good healthchemistry.chemical_compoundchemistryGeneral Materials ScienceMetal-organic frameworkCristallsLuminescenceMaterials
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CCDC 1916087: Experimental Crystal Structure Determination

2019

Related Article: María Cabrero-Antonino, Sonia Remiro-Buenamañana, Manuel Souto, Antonio A. García-Valdivia, Duane Choquesillo-Lazarte, Sergio Navalón, Antonio Rodríguez-Diéguez, Guillermo Mínguez Espallargas, Hermenegildo García|2019|Chem.Commun.|55|10932|doi:10.1039/C9CC04446A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-1H-benzotriazolato-5-carboxylato)-bis(mu-hydroxo)-tri-zinc(ii) NN-dimethylformamide unknown solvate]Experimental 3D Coordinates
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CCDC 1916085: Experimental Crystal Structure Determination

2019

Related Article: María Cabrero-Antonino, Sonia Remiro-Buenamañana, Manuel Souto, Antonio A. García-Valdivia, Duane Choquesillo-Lazarte, Sergio Navalón, Antonio Rodríguez-Diéguez, Guillermo Mínguez Espallargas, Hermenegildo García|2019|Chem.Commun.|55|10932|doi:10.1039/C9CC04446A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-1H-benzotriazolato-5-carboxylato)-bis(mu-hydroxo)-tri-zinc(ii) NN-dimethylformamide solvate monohydrate]Experimental 3D Coordinates
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CCDC 1916082: Experimental Crystal Structure Determination

2019

Related Article: María Cabrero-Antonino, Sonia Remiro-Buenamañana, Manuel Souto, Antonio A. García-Valdivia, Duane Choquesillo-Lazarte, Sergio Navalón, Antonio Rodríguez-Diéguez, Guillermo Mínguez Espallargas, Hermenegildo García|2019|Chem.Commun.|55|10932|doi:10.1039/C9CC04446A

Space GroupCrystallographycatena-[bis(mu-1H-benzotriazolato-5-carboxylato)-bis(mu-hydroxo)-tri-zinc(ii) tetrahydrate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1916084: Experimental Crystal Structure Determination

2019

Related Article: María Cabrero-Antonino, Sonia Remiro-Buenamañana, Manuel Souto, Antonio A. García-Valdivia, Duane Choquesillo-Lazarte, Sergio Navalón, Antonio Rodríguez-Diéguez, Guillermo Mínguez Espallargas, Hermenegildo García|2019|Chem.Commun.|55|10932|doi:10.1039/C9CC04446A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-benzotriazolato-6-carboxylato)-(mu-hydroxo)-(mu-oxido)-(mu-formato)-tetra-zinc]Experimental 3D Coordinates
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CCDC 1916086: Experimental Crystal Structure Determination

2019

Related Article: María Cabrero-Antonino, Sonia Remiro-Buenamañana, Manuel Souto, Antonio A. García-Valdivia, Duane Choquesillo-Lazarte, Sergio Navalón, Antonio Rodríguez-Diéguez, Guillermo Mínguez Espallargas, Hermenegildo García|2019|Chem.Commun.|55|10932|doi:10.1039/C9CC04446A

catena-[bis(mu-1H-benzotriazolato-5-carboxylato)-bis(mu-hydroxo)-tri-zinc(ii) NN-dimethylformamide solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1916083: Experimental Crystal Structure Determination

2019

Related Article: María Cabrero-Antonino, Sonia Remiro-Buenamañana, Manuel Souto, Antonio A. García-Valdivia, Duane Choquesillo-Lazarte, Sergio Navalón, Antonio Rodríguez-Diéguez, Guillermo Mínguez Espallargas, Hermenegildo García|2019|Chem.Commun.|55|10932|doi:10.1039/C9CC04446A

catena-[bis(mu-1H-benzotriazolato-5-carboxylato)-bis(mu-hydroxo)-tri-zinc(ii) NN-dimethylformamide solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct