6533b82efe1ef96bd1293dac

RESEARCH PRODUCT

Interpenetrated Luminescent Metal-Organic Frameworks based on 1H-Indazole-5-carboxylic Acid

Guillermo Mínguez EspallargasJosé ÁNgel GarcíaMarcos González-tejeroBelén FernándezDuane Choquesillo-lazarteManuel SoutoManuel SoutoAntonio Rodríguez-diéguezManuel Pérez-mendozaJavier CepedaAntonio A. García-valdivia

subject

chemistry.chemical_classificationIndazole010405 organic chemistryCarboxylic acidGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesCombinatorial chemistry0104 chemical sciences3. Good healthchemistry.chemical_compoundchemistryGeneral Materials ScienceMetal-organic frameworkCristallsLuminescenceMaterials

description

Herein we report the formation and characterization of two novel Zn-based multifunctional metal-organic frameworks (MOFs) based on 1H-indazole-5-carboxylic acid and bipyridine-like linkers, synthesized by soft solvothermal routes. These materials possess isoreticular 2-fold interpenetrated three-dimensional structures that afford a flexible character and allow porosity modulation of the MOFs as confirmed by CO2 sorption measurements. Apart from this attractive structural feature, the MOFs exhibit fascinating luminescent properties involving both luminescence thermometry and long-lasting phosphorescence.

yearjournalcountryeditionlanguage
2020-05-13
10.1021/acs.cgd.0c00345https://hdl.handle.net/10550/79917