Analytic density-functionals with initial-state dependence and memory

2013

We analytically construct the wave function that, for a given initial state, produces a prescribed density for a quantum ring with two noninteracting particles in a singlet state. In this case the initial state is completely determined by the initial density, the initial time derivative of the density and a single integer that characterizes the (angular) momentum of the system. We then give an exact analytic expression for the exchange-correlation potential that relates two noninteracting systems with different initial states. This is used to demonstrate how the Kohn-Sham procedure predicts the density of a reference system without the need of solving the reference system’s Schrodinger equa…